Detection of nitrate sources in urban groundwater by isotopic and chemical indicators,Hangzhou City,China

The sources of nitrate in the shallow groundwater at urban area, Hangzhou City, China were investigated using chemical and isotopic techniques. Groundwater electric conductivity was high in the study area and ranged from 369–1,544 S/cm. Most of the groundwater was weakly alkaline and the groundwater chemistry was seriously influenced by land use in the city. There was a high frequency of groundwater (43% of total) with nitrate above World Heath Organizations standards of 10 mg NO₃/L. The different land-use areas had different nitrate concentrations (0.04–34.41 mgN/L) and ¹⁵N _NO3 values (7.8~35.5). Domestic wastewater was the major nitrate source of shallow groundwater in the urban area, and the point source (septic tank) still existed in residential settings. At agricultural settings manure was the major NO₃ sources. High ¹⁵N _NO3 value (>20) and temporal variations of the ¹⁵N _NO3 value suggested that in residential areas it probably resulted from denitrification.     

Flood damage assessment of an urban area in Chennai, India, part I: methodology

Floods are random phenomena that not only cause damage to the lives, natural resources and the environment, but also affect the health of people. The severity of flooding tends to increase with urbanization. Socio-economic impacts of floods depend on the area, duration and depth of inundation, population density, housing typology, construction materials of dwellings, etc. This article examines the different available methods to trace the flood damage and illustrates the methodology to explore the economic loss through social investigation in Velachery, a part of urban Chennai in India. This paper is Part I of a two-part series in which the objectives and methodology are discussed. Based on the objectives and methodology developed for the study, a comprehensive flood management strategy can be proposed for the efficient management of future flood disasters. The results of the study are discussed in Part II.     

塔北哈拉哈塘地区奥陶系层间改造区岩溶古水文条件分析

哈拉哈塘地区自北往南可分为潜山岩溶区、层间岩溶顺层改造区、层间岩溶台缘叠加区、层间岩溶斜坡区。层间岩溶-顺层改造区为潜山岩溶区和层间岩溶区过渡区域,文章对前志留纪和良里塔格组岩溶期沉积间断古岩溶水文条件特征进行了详细分析,认为地表河流特征总体表现为自北往南径流,深切河谷决定着局部排泄基准面的深度。在此基础上对地下暗河特征进行刻画,本区地下暗河类型多样,总体表现为流入型和流出型暗河管道系统发育,多为单流入、流出系统,地震反射暗河特征较明显,多为连续或断续串珠强反射,以良里塔格组岩溶期暗河最为发育,且前志留纪岩溶期“断头河”多为部分伏流出口。地下暗河管道附近往往发育大型缝洞体,是目前勘探开发重点研究攻坚对象,因此精确恢复和刻画古岩溶流域水文系统的分布特征,寻找油气藏有利储层是广大岩溶油藏专家所关注的重点。      

A source and ground motion study of earthquakes in and near Delhi (the National Capital Region), India

Natural Hazards - We study source parameters of 10 local earthquakes (2.7 ≤  $$M_{w}$$ ≤ 4.5) that have occurred in the National Capital Region (NCR) since 2001 and...     

Characterization and sources of extractable organic matter from sediment cores of an urban lake (Tasik Perdana), Kuala Lumpur,Malaysia

The extractable organic matter of sediment samples from six sampling sites in Lake Perdana, Kuala Lumpur, was analyzed to characterize the source inputs. The analysis of aliphatic homologous series indicated that terrestrial higher plant waxes can be assigned as the major sources of the identified aliphatic components in the lake sediments. The presence of an unresolved complex mixture of branched and cyclic compounds and a series of hopanes ranging from C₂₇ to C₃₅ reflected the contamination by petroleum residues from urban vehicular emissions brought in by runoff and fallout. The steroids present included stenols and stanols and showed an input of organic matter from higher plants. The detected pentacyclic triterpenoids comprised oleanane, ursane, lupane and friedelane skeletons including unsaturated oxygenated, mono-, di- and triaromatic counterparts. They are recognized as biomarkers for angiosperms. The presence of des-A-triterpenoids and their aromatized derivatives as the major diagenetic products of triterpenoids reflected the degradation of natural organic matter in the sediments occurring under mainly anoxic conditions. In addition, the presence of tetrahymanol and ββ-bishomohopan-32-ol indicated a minor algal/plankton and bacterial input to the sediments.     

Sources of dissolved ions revealed by chemical and isotopic tracers in the Geum River,South Korea

Water samples were collected in the main channel of the Geum River, South Korea, and measured dissolved elemental concentrations and isotopic compositions of nitrate in order to identify the factors controlling water chemistry. Elemental concentrations significantly increased location-wise after the confluence from urban areas, indicating the changes in solute sources from chemical weathering to anthropogenic inputs such as manure, fertilizers, and sewage. In particular, the effect of sewage input is manifested in the concentrations of Cl^?, SO₄ ^2?, and Na⁺, while the NO₃ ^? concentration is influenced mainly by soil inputs with minor contributions from manure and fertilizer because both δ¹⁵N–NO₃ and δ¹⁸O–NO₃ indicate NO₃ ^? mostly consists of soil-derived nitrates in the upper reaches but manure/sewage nitrates in the lower reaches. The relative proportion of three factors, Cl^?, Ca²⁺+Mg²⁺, and NO₃ ^?, indicates that water chemistry in the upstream is controlled by the soil weathering but that in the downstream by the sewage. Seasonally, water chemistry during summer is dominated by the soil weathering due to the flushing effect but that during winter by the sewage. This study suggests that the relative proportion of three factors can be used for tracing natural and anthropogenic sources in water chemistry.     

Evaluation of groundwater quality for irrigation and drinking using GIS and geostatistics in a peri-urban area of Delhi, India

Intensive agriculture by indiscriminate use of agrochemicals, sewage water, and polluted drain water has posed a serious threat to groundwater quality in some peri-urban areas of Delhi like Najafgarh block. The objective of the study was to determine the groundwater quality and to map their spatial variation in terms of suitability for irrigation and drinking purpose. Ordinary kriging method was used for preparation of thematic maps of groundwater quality parameters such as electrical conductivity, sodium adsorption ratio, bicarbonate, magnesium/calcium ratio, total dissolved solids, chloride, nitrate and hardness. Exponential semivariogram model was best fitted for all quality parameters except chloride and hardness, where spherical model fitted best. Pollution level was highest at south and south-eastern part of the study area. Better quality groundwater may be expected at the northern and western part. High salinity was due to high chloride concentration in the groundwater. Nitrate pollution level was found to be very alarming and need immediate interventions. High dissolved solids and hardness made the groundwater unsuitable for drinking. There were negligible sodium and bicarbonate hazard in the study area. The groundwater quality index was devised to analyse the combined impact of different quality parameters on irrigation and drinking purposes. The irrigation water quality index and drinking water quality index distribution maps delineated an area of 47.29 and 6.54 km² suitable for irrigation and drinking, respectively. These safe zones were found as a small strip along the northern boundary and a very small pocket at the western side of the study area.     

Identification of groundwater potential zones within an area with various geomorphological units by using several field parameters and a GIS approach in Kulon Progo Regency, Java, Indonesia

A case study was conducted to find the groundwater potential zones in an area between the Serang and Bogowonto rivers, Kulon Progo Regency, Java, Indonesia. The objectives of this study were to delineate the groundwater potential zone based on a number of groundwater parameters that can be surveyed in the field and to incorporate the geomorphological conditions into these data. The geomorphology interpretation was conducted using the landform approach. This approach begins by preparing supporting data such as an Indonesian Topographic Map containing contour and land use data; a regional geology map containing lithology type and geology structures; and soil, climate, and hydrological data. The determination of the geomorphology unit was conducted manually by the visual interpretation of Digital Landsat ETM⁺ with some image interpretation keys. Four groundwater parameters were surveyed in the field: (a) depth to the water table, (b) water table fluctuation, (c) fluid electrical conductivity to represent groundwater quality, and (d) aquifer thickness. The groundwater potential zones were obtained by overlaying all the groundwater field parameters in terms of weighted overlay methods using the spatial analysis tool in ArcGIS 9.2. During the weighted overlay analysis, rankings were produced for each individual parameter of each groundwater field parameter, and weights were assigned based on the amount of influence they had (i.e., depth to the water table—30 %, water table fluctuation—20 %, aquifer thickness—30 %, and fluid conductivity—20 %). We then found the good, moderate, and poor zones in terms of groundwater potential, which had areas of 5.83, 4.53, and 2.36 km², respectively. Areas with good groundwater potential are located largely within sand dunes, beach ridges, beaches, and fluviomarine plain landforms, which are characterized by a shallow water table, low fluctuation, thick aquifer, and low EC value. Moderate groundwater zones are generally characterized by poor water quality (high EC value), which is found to some degree in the alluvial plain. The regions with poor groundwater potential are spread mainly across the landforms composed of igneous rock (thin aquifers), such as denudational hills, which act as run-off zones due to their steep slope.     

Use of isotopic tracers to characterize the interaction of water components and nitrate contamination in the arid Rasafeh area (Syria)

Chemical and isotopic data in atmospheric precipitation, surface water, and groundwater in arid Rasafeh area, northeast Syria, are used to clarify the status of groundwater quality, the interaction of water components, groundwater dating, and vulnerability to anthropogenic contamination. Interpretation of chemical data with thermodynamic calculation reveals that the dissolution of evaporate mineral is the main factor of high salinity. The δ¹⁸O and δ²H relationships indicate that the groundwater is fed by mixing water from Euphrates River and precipitation and the isotope balance equation were used to estimate the contribution of the Euphrates River to the aquifers recharge. High tritium content, together with high ¹⁴C activity in the majority of groundwater samples, indicate shorter residence times and consequently potentially greater recharge. The presence of high nitrate concentration associated with high tritium concentration in both shallow and deep aquifer units indicates the presence of high permeability, so that groundwater is highly susceptible to anthropogenic contamination. Nitrate seems to derive exclusively from the application of N fertilizers. The high nitrate values are characteristic of the areas with intensive agricultural activity, indicating the importance of irrigated return flow on the groundwater.     

A geochemical and isotopic assessment of hydraulic connectivity of a stacked aquifer system in the Lisbon Valley,Utah (USA), and critical evaluation of environmental tracers

Hydrogeology Journal - This study investigates hydraulic connectivity of a stacked aquifer system in the Lisbon Valley of southeastern Utah (USA), within the Paradox Basin, where numerous faults...     

新疆叶尔羌河流域地下水同位素特征及其补给来源分析

笔者以新疆叶尔羌河流域为例,在研究区水文地质调查的基础上,根据不同区域、不同深度D、~(18)O和T值的变化分析地下水补给来源.解决了传统研究方法很难解决的问题.为干旱地区地下水起源及空间分布规律研究提供了新思路。研究结果表明:(1)研究区地下水不是来自大气降水的直接入渗,而是地表水渗漏补给。(2)流域分为两个独立的地下水循环系统,分别接受叶尔羌河与提孜那甫河河水补给。(3)潜水和承压水的起源相同,属统一的地下水系统。(4)地下水径流表现为倾斜平原区径流强烈,地下水以水平运动为主;细土平原区地下水径流迟缓,地下水以垂直蒸发运动为主.径流方向与地表水流向密切相关。     

Environmental impact assessment in the Moradabad industrial area (rivers Ramganga-Ganga interfluve), Ganga Plain,India

Sediment samples collected in the Moradabad area, lying in the interfluve of the Ganga and Ramganga Rivers, were analysed for heavy metals, after studying the geomorphology of the area. Geomorphologically, the area can be divided into three terraces - the T₀, T₁ and T₂ surfaces. The rivers on these three surfaces show varying amounts of pollution depending upon the input from industries and urban settlements. The Ramganga River on the T₀ surface shows the highest amount of pollution. However, the pollution levels in all these rivers show a downstream dilution effect. The characteristic feature of the vast interfluve area (T₂ surface) is the presence of several, independent basins which are closed and rarely interact with each other or with any river. The sediments are redistributed and redeposited within the basin itself, and thus these basins serve as sinks. The sediments of one such basin in the study area show significant concentrations of arsenic, chromium, copper, nickel, lead, zinc and organic carbon. The concentrations of heavy metals in such a basin will show exponential increases with time, because there is no activity to funnel out the sediments and dilute the effect of pollution. This increase will pose more threats, as ultimately it will make its way laterally and vertically through the sediments, thereby polluting groundwater.     

Concentration of arsenic by selected vegetables cultivated in the Yamuna flood plains (YFP) of Delhi,India

High Arsenic (As) concentrations have been reported in superficial water in the Yamuna flood plains (YFP), Delhi, which is being extensively used for agriculture. The concentration of As in some common vegetables such as Solanum lycopersicum (tomato), Abelmoschus esculentus (lady’s finger), Solanum melongena (brinjal), Lagenaria siceraria (bottle gourd), Raphanus sativus (radish), Zea mays (corn), and Luffa acutangula (ridge gourd) has been studied in this work. The range of As concentrations (dry weight) varies from 0.6 to 2.52 mg/kg with the highest accumulation of 2.52 mg/kg in radish followed by tomato (2.36 mg/kg). The order of As concentration in the decreasing order is R. sativus > S. lycopersicum > Z. mays > L. acutangula > L. siceraria > S. melongena > A. esculentus. Thus, As accumulation is the highest in roots and the lowest in least juicy fruits. The daily dietary intake of As through the consumption of various vegetables was also calculated. Though the mean As concentration was the highest in radish (2.52 mg/kg) but the highest amount of As is being consumed through tomato (0.383 mg/day), which is nearly three times the World Health Organization’s provisional maximum tolerable daily intake limit of 0.126 mg/day for a 60 kg person. High concentration of As in vegetables grown in YFP, Delhi is being reported here. This high contamination is primarily due to the presence of As in irrigation water having its source from coal-based thermal power plants in the vicinity of the area. If not checked properly, it will pose a serious health risk to people living in these densely populated areas surrounding YFP.