Noble-gas evidence for geothermal activity in a karstic terrain: Rocky Mountains,Canada.

Geothermally heated fluids are identified as a component in warm (up to 54°C) springs in the southern Canadian Rocky Mountains. High concentrations of radiogenic He (10^?3 ccSTP/cc gas) and atmospheric Ne, Ar, Kr and Xe in the gases that vigorously bubble at the Fairmont Hot Spring, assign the latter to be a “drowned” fumarole, fed by geothermal steam. Up to 75% depletions in the atmospheric noble gases in several warm springs indicate contributions of residual geothermal water. On the other hand, in a few cases noble gases were found in excess (W) over the expected concentrations in airequilibrated recharge water. The observed “reversed” pattern of w_nc >W_Ar >W_kr >W_xe is interpreted as excess air, incorporated during recharge through karstic conduits. The mixing ratios of geothermal and karstic waters can be deduced.     

Effect of Water and Leachate on Hydraulic Behavior of Compacted Bentonite,Calcareous Sand and Tuff Mixtures for Use as Landfill Liners

Compacted soil–bentonite liners, consisting of a sandy soil mixed with bentonite as backfill, are used extensively as engineered barriers for contaminant containment. This paper studies the valorization of local materials containing calcareous sand, tuff obtained from Laghouat region (in the South Algeria), to associate with bentonite in order to improve their hydraulic characteristics for use as landfill liner material. Firstly, a geotechnical characterization of mixtures chooses from a fixed percentage to 10% bentonite and different percentages of calcareous sand and tuff so that they are complementary to 90% by not 10%. Thereafter, the determination of saturated hydraulic conductivity at falling-head permeability (K_v) and oedometer (K_id, indirect Measure) tests of all compacted mixtures at Optimum Normal Proctor have been carried out using both permeates by tap water and a landfill leachate in order to simulate long-term conditions. The results showed that the saturated hydraulic conductivity of tap water is relatively lower than the one saturated by leachate in the falling-head test, unlike the oedometer test. The B₁₀CS₂₀T₇₀ mixture has satisfied the hydraulic conductivity criterion of bottom barriers (i.e. water permeated: k_v20° = 1.97 × 10^?9 and k_id from 7 × 10^?9 to 1.83 × 10^?10 < 10^?9m/s; leachate permeated: k_v20° = 2.91 × 10^?9 and k_id from 7 × 10^?9 at 1.44 × 10^?10 < 10^?9 m/s). Finally, a comparison between direct measurements of the saturated hydraulic conductivity by triaxial (K_d) test and oedometer test (K_id) in the range of effective stress applied 100–800 kPa led to propose equations of correlations between these two methods. In conclusion, adopted formulation B₁₀CS₂₀T₇₀ perfectly meets the regulatory requirements in force and constitutes an economic product based on available local materials for engineers barriers.     

Carbon dioxide degassing and thermal energy release in the Monte Amiata volcanic-geothermal area (Italy)

The quaternary volcanic complex of Mount Amiata is located in southern Tuscany (Italy) and represents the most recent manifestation of the Tuscan Magmatic Province. The region is characterised by a large thermal anomaly and by the presence of numerous CO₂-rich gas emissions and geothermal features, mainly located at the periphery of the volcanic complex. Two geothermal systems are located, at increasing depths, in the carbonate and metamorphic formations beneath the volcanic complex. The shallow volcanic aquifer is separated from the deep geothermal systems by a low permeability unit (Ligurian Unit). A measured CO₂ discharge through soils of 1.8 × 10⁹ mol a⁻¹ shows that large amounts of CO₂ move from the deep reservoir to the surface. A large range in δ¹³C_TDIC (−21.07 to +3.65) characterises the waters circulating in the aquifers of the region and the mass and isotopic balance of TDIC allows distinguishing a discharge of 0.3 × 10⁹ mol a⁻¹ of deeply sourced CO₂ in spring waters. The total natural CO₂ discharge (2.1 × 10⁹ mol a⁻¹) is slightly less than minimum CO₂ output estimated by an indirect method (2.8 × 10⁹ mol a⁻¹), but present-day release of 5.8 × 10⁹ mol a⁻¹ CO₂ from deep geothermal wells may have reduced natural CO₂ discharge. The heat transported by groundwater, computed considering the increase in temperature from the infiltration area to the discharge from springs, is of the same order of magnitude, or higher, than the regional conductive heat flow (>200 mW m⁻²) and reaches extremely high values (up to 2700 mW m⁻²) in the north-eastern part of the study area. Heat transfer occurs mainly by conductive heating in the volcanic aquifer and by uprising gas and vapor along fault zones and in those areas where low permeability cover is lacking. The comparison of CO₂ flux, heat flow and geological setting shows that near surface geology and hydrogeological setting play a central role in determining CO₂ degassing and heat transfer patterns.     

Characteristics of the geothermal water in Changbai Mountain volcanic region,northeast of China

Geothermal water is plentiful in Changbai Mountain region, northeastern China, due to the volcanic activities and widespread faults. For the exploration of geothermal resources, this study uses quartz and cation geothermometer to estimate the temperatures of the geothermal reservoir and uses the tubular models to evaluate the thermal gradient. The hydrogeochemical characteristics of the geothermal resources were also evaluated by hydrogeochemical analysis. The results showed that the geothermal reservoir temperatures of the four major thermal springs in Changbai Mountain region range from 72 to 169 °C. The average geothermal reservoir temperatures of Jinjiang hot springs, Changbai hot springs I, Xianrenqiao hot springs, and Changbai hot springs II are 129.25, 169, 89, and 73.67 °C, respectively. The geothermal gradient values of the four major thermal springs have different characteristics. The geothermal gradient values of Jinjiang hot springs and Changbai hot springs I are 4.6 and 3.1 °C/100 m, respectively. The geothermal gradient values of Xianrenqiao thermal springs and Changbai thermal springs II are both lower than 1.5 °C/100 m, with the values of 1.1 and 1.4 °C/100 m. And the geothermal gradients are influenced by Changbai Mountain Tianchi volcano. In addition, the water chemical analyses showed that the geothermal water types are HCO₃-Na with higher concentrations of Na⁺, Cl^?, SO₄ ^2?, TDS, and HCO₃ ^? than the non-thermal waters, which suggested a deep and long water cycle of the thermal water, and therefore a sufficient water-rock interaction.     

Large-scale hydraulic conductivity distribution in an unconfined carbonate aquifer using the ocean tidal propagation

The hydraulic conductivity of an unconfined carbonate aquifer at the uplifted atoll of Minami-Daito, Japan, was evaluated by a combination of cross-spectral analysis, analytical solution, and density-dependent groundwater modeling based on observed groundwater levels in 15 wells and at sea level. The island area was divided into 10 subregions based on island morphology and on inland propagation of ocean tides. The hydraulic conductivity was obtained for each subregion using analytical solutions based on phase lags of M₂ constituents of ocean tides at each well by assuming two aquifer thicknesses (300 and 1,800 m) and two effective porosities (0.1 and 0.3). The density-dependent groundwater model evaluated the hydraulic conductivity of the subregions by reproducing observed groundwater levels. The hydraulic conductivity in the subregions was estimated as 3.46?×?10^?3 to 6.35?×?10^?2 m/s for aquifer thickness of 300 m and effective porosity of 0.1, and as 1.73?×?10^?3 to 3.17?×?10^?2 m/s for aquifer thickness of 1,800 m and the effective porosity of 0.3. It was higher in southern and northern areas, and higher in interior lowland than in the western and eastern areas. Fissures and dolomite distributions on the island control differences of the omnidirectional ocean tidal propagation and cause these differences in hydraulic conductivity. The method used for this study may also be applicable to other small islands that have few or no data for hydraulic conductivity.

     

Numerical simulations to assess thermal potential at Tauranga low-temperature geothermal system,New Zealand

Tauranga low-temperature geothermal system (New Zealand) has been used for the last 40 years for direct uses including space heating, bathing and greenhouses. Warm-water springs in the area are between 22 and 39 °C, with well temperatures up to 67 °C at 750 m depth. A heat and fluid flow model of the system is used to determine reservoir properties and assess thermal potential. The model covers 130 km by 70 km to 2 km depth, and was calibrated against temperatures measured in 17 wells. Modelling shows that to maintain the observed primarily conductive heat flow regime, bulk permeability is ≤2.5?×?10^?14 m² in sedimentary cover and ≤1?×?10^?16 m² in the underlying volcanic rocks. The preferred model (R ²?=?0.9) corresponds to thermal conductivities of 1.25 and 1.8 W/m² for sedimentary and volcanic rocks, respectively, and maximum heat flux of 350 mW/m². The total surface heat flow is 258 MW over 2,200 km². Heat flux is highest under Tauranga City, which may be related to inferred geology. Model simulations give insights into rock properties and the dynamics of heat flow in this low-temperature geothermal system, and provide a basis to estimate the effects of extracting hot fluid.     

Geochemical constraint on origin and evolution of solutes in geothermal springs in western Yunnan,China

Geothermal resources are very rich in Yunnan, China. However, source of dissolved solutes in geothermal water and chemical evolution processes remain unclear. Geochemical and isotopic studies on geothermal springs and river waters were conducted in different petrological-tectonic units of western Yunnan, China. Geothermal waters contain Ca–HCO₃, Na–HCO₃, and Na (Ca)–SO₄ type, and demonstrate strong rock-related trace elemental distributions. Enhanced water–rock interaction increases the concentration of major and trace elements of geothermal waters. The chemical compositions of geothermal waters in the Rehai geothermal field are very complicated and different because of the magma chamber developed at the shallow depth in this area. In this geothermal field, neutral-alkaline geothermal waters with high Cl, B, Li, Rb Cs, As, Sb, and Tl contents and acid–sulfate waters with high Al, Mn, Fe, and Pb contents are both controlled by magma degassing and water–rock interaction. Geothermal waters from metamorphic, granite, and sedimentary regions (except in the Rehai area) exhibit varying B contents ranging from 3.31 mg/L to 4.49 mg/L, 0.23 mg/L to 1.24 mg/L, and <0.07 mg/L, respectively, and their corresponding δ¹¹B values range from −4.95‰ to −9.45‰, −2.57‰ to −8.85‰, and −4.02‰ to +0.06‰. The B contents of these geothermal waters are mainly controlled by leaching host rocks in the reservoir, and their δ¹¹B values usually decrease and achieve further equilibrium with its surrounding rocks, which can also be proven by the positive δ¹⁸O-shift. In addition to fluid–rock reactions, the geothermal waters from Rehai hot springs exhibit higher δ¹¹B values (−3.43‰ to +1.54‰) than those yielded from other areas because mixing with the magmatic fluids from the shallow magma. The highest δ¹¹B of steam–heated waters (pH 3.25) from the Zhenzhu spring in Rehai is caused by the fractionation induced by pH and the phase separation of coexisting steam and fluids. Given the strong water–rock interaction, some geothermal springs in western Yunnan show reservoir temperatures higher than 180 °C, which demonstrate potential for electricity generation and direct-use applications. The most potential geothermal field in western Yunnan is located in the Rehai area because of the heat transfer from the shallow magma chamber.     

Hydraulic properties of the crystalline basement

Hydraulic tests in boreholes, up to 4.5 km deep, drilled into continental crystalline basement revealed hydraulic conductivity (K) values that range over nine log-units from 10⁻¹³−10⁻⁴ m s⁻¹. However, K values for fractured basement to about 1 km depth are typically restricted to the range from 10⁻⁸ to 10⁻⁶ m s⁻¹. New data from an extended injection test at the KTB research site (part of the Continental Deep Drilling Program in Germany) at 4 km depth provide K=5 10⁻⁸ m s⁻¹. The summarized K-data show a very strong dependence on lithology and on the local deformation history of a particular area. In highly fractured regions, granite tends to be more pervious than gneiss. The fracture porosity is generally saturated with Na–Cl or Ca–Na–Cl type waters with salinities ranging from <1 to >100 g L⁻¹. The basement permeability is well within the conditions for advective fluid and heat transport. Consequently, fluid pressure is hydrostatic and a Darcy flow mechanism is possible to a great depth. Topography-related hydraulic gradients in moderately conductive basement may result in characteristic advective flow rates of up to 100 L a⁻¹ m⁻² and lead to significant advective heat and solute transfer in the upper brittle crust. An erratum to this article can be found at     

A preliminary study on the potential of the geothermal resources around the Gulf of Suez, Egypt

The Gulf of Suez is characterized by the presence of many hot springs and deep thermal wells scattered around its coastal areas. So it is considered one of the promised geothermal areas in Egypt. In this study, the main emphasis is to investigate the geothermal potential around the Gulf of Suez using the available logging and geothermometer datasets. The temperature profiles and well logging data of some hot springs and deep wells around or within the coastal area of the Gulf of Suez are used in this study. The temperature profiles are analyzed and some important thermophysical properties are estimated (geothermal gradient, thermal conductivity, heat flow, and specific heat capacity). Such analysis revealed that a medium to high geothermal gradient (22.0–30°C/Km) is given for the Gulf of Suez as a whole, with some spots of much higher gradient in the order of 35.0–44°C/Km (Ras Fanar and Hammam Faraun areas). The compiled thermal plots show that the thick evaporites and rock salt lithology, which is a major constituent in this area, attain the highest thermal conductivity (>3.10 W/m/K) and heat flow (>90 mW/m²) and the lowest specific heat capacity (<0.30 J/kg/K). The available gamma ray and the natural gamma ray spectroscopy logs are used to conduct a radioactive-based heat generation study using the characteristic radioactive nature of some elements like; ²³⁸U, ²³⁵U, ²³²Th, and of the isotope of ⁴⁰K. A good linearity is observed between the heat production (A in microwatt per cubic meter) and the gamma ray (API) along a wide range of datasets (0–150 API) in all wells. The heat production factor increases in the carbonate lithology (up to 3.20?μW/m³) and is proportional to the shale volume. A geothermometer-based study is used to estimate the subsurface formation temperature and heat flow from the geochemical analysis of some water samples collected from the studied hot springs. The estimated thermal parameters are in harmony with the regional thermal regime concluded form logging data. A thermal basin growth study, in relation to the clay diagenesis is conducted concerning the thermal effects that take place with depth giving rise to another clay mineral (illite). Furthermore, a number of 2D thermal–burial history diagrams are constructed for the complied sections of some of the studied areas to show the vertical distribution of the estimated petrothermal properties. A reserve evaluation study is carried out to estimate the economic geothermal capacity of these hot springs to be used as alternative clean source for possible energy production (electricity) and other low-temperature purposes.     

Characterization of mean transit time at large springs in the Upper Colorado River Basin,USA: a tool for assessing groundwater discharge vulnerability

Environmental tracers (noble gases, tritium, industrial gases, stable isotopes, and radio-carbon) and hydrogeology were interpreted to determine groundwater transit-time distribution and calculate mean transit time (MTT) with lumped parameter modeling at 19 large springs distributed throughout the Upper Colorado River Basin (UCRB), USA. The predictive value of the MTT to evaluate the pattern and timing of groundwater response to hydraulic stress (i.e., vulnerability) is examined by a statistical analysis of MTT, historical spring discharge records, and the Palmer Hydrological Drought Index. MTTs of the springs range from 10 to 15,000 years and 90 % of the cumulative discharge-weighted travel-time distribution falls within the range of 2?10,000 years. Historical variability in discharge was assessed as the ratio of 10–90 % flow-exceedance (R _10/90%) and ranged from 2.8 to 1.1 for select springs with available discharge data. The lag-time (i.e., delay in discharge response to drought conditions) was determined by cross-correlation analysis and ranged from 0.5 to 6 years for the same select springs. Springs with shorter MTTs (<80 years) statistically correlate with larger discharge variations and faster responses to drought, indicating MTT can be used for estimating the relative magnitude and timing of groundwater response. Results indicate that groundwater discharge to streams in the UCRB will likely respond on the order of years to climate variation and increasing groundwater withdrawals.     

Spatial characteristics of groundwater temperature in the Ishikari Lowland, Hokkaido, northern Japan: analytical and numerical applications

In porous sediments of the Ishikari Lowland, there is a gradual increase in the background geothermal gradient from the Ishikari River (3–4 °C 100 m^–1) to the southwest highland area (10 °C 100 m^–1). However, the geothermal gradient at shallow depths differs in detail from the background distribution. In spite of convective heat-flow loss generally associated with groundwater flow, heat flow remains high (100 mW m^–2) in the recharge area in the southwestern part of the Ishikari basin, which is part of an active geothermal field. In the northeastern part of the lowland, heat flow locally reaches 140 mW m^–2, probably due to upward water flow from the deep geothermal field. Between the two areas the heat flow is much lower. To examine the role of hydraulic flow in the distortion of the isotherms in this area, thermal gradient vs. temperature analyses were made, and they helped to define the major components of the groundwater-flow system of the region. Two-dimensional simulation modeling aided in understanding not only the cause of horizontal heat-flow variations in this field but also the contrast between thermal properties of shallow and deep groundwater reservoirs. Electronic Publication     

Effect of organic acids and fluoride on the dissolution kinetics of hydrous alumina. A model study using the rotating disc electrode

The dissolution of aluminium oxide was studied with an oxide film covered rotating disc aluminium electrode. This allows us to make measurements under conditions of well defined mass transport under conditions representative of those found in natural waters (conc. of Al, organic acids and fluoride), and permits us to distinguish between surface-controlled and transport-controlled rates.Under steady-state conditions, the dissolution current is a direct measure of the flux of dissolving Al ions at the aqueous interface of the amorphous hydrous oxide film.At pH 3–6 and in presence of organic ligands, dissolution is controlled by a surface process, i.e. the rate of detachment of surface complexes. Fluoride ions in concentrations ≥ 10^?6 M increase dramatically the dissolution rate: at pH = 4 the process is controlled by convertive diffusion of F^? from the solution to the surface (k_F- = (3.6 ± 0.5) × 10^?2cms^?1). Competitive and reversible adsorption of organic ligands (10^?6 ? 10^?2M) displacing fluoride slows down the rate of detachment of the surface complex which becomes the rate-limiting step. The affinity of ligands for the Al₂O₃ surface sites increases in the sequence: formate ~ chloride ~ carbonate < acetate < sulphate < salicylate < fumarate < maleate < malonate ? oxalate ? fluoride ≤ citrate.The results are compared with simulated weathering experiments and interpreted in terms of the surface complexation model.     

Geochemical,isotopic and hydrological mass balance approaches to constrain the lake water–groundwater interaction in Dal Lake,Kashmir Valley

It is important to have qualitative as well as quantitative understanding of the hydraulic exchange between lake and groundwater for effective water resource management. Dal, a famous urban fresh water lake, plays a fundamental role in social, cultural and economic dynamics of the Kashmir Valley. In this paper geochemical, isotopic and hydrological mass balance approaches are used to constrain the lake water–groundwater interaction of Dal Lake and to identify the sources of lake water. Water samples of precipitation (n = 27), lake water (n = 18) and groundwater (n = 32) were collected across the lake and its catchment for the analysis of δ¹⁸O and δ²H. A total of 444 lake water samples and 440 groundwater samples (springs, tube wells and dug wells) were collected for the analysis of Ca²⁺, Mg²⁺, HCO₃ ^?, SO₄ ^2?, Cl^?, NO₃ ^?, Na⁺ and K⁺. Water table and lake water level were monitored at 40 observation locations in the catchment. Water table map including pH and EC values corroborate and verify the gaining nature of the Dal Lake. Stable isotopes of lake water in Boddal and Gagribal basins showed more deviation from the global meteoric water line than Hazratbal and Nigeen basins, indicating the evaporation of lake water. The isotopic and geochemical mass balance suggested that groundwater contributes a significant proportion (23–40%) to Dal Lake. The estimated average groundwater contribution to Dal Lake ranged from 31.2 × 10³ to 674 × 10³ m³ day^?1 with an average of 276 × 10³ m³ day^?1. The study will be useful to delineate the possible sources of nutrients and pollutants entering the lake and for the management of lake water resources for sustainable development.     

天津地区雾迷山组地热资源潜力区划

天津地区属于典型的中低温沉积盆地型地热区,地热资源丰富,现已被广泛地应用于地热供暖、生活用水、温泉洗浴等各个方面,取得了显著的社会经济效益。雾迷山组地热资源在天津地区分布广泛,是天津地区最主要的开采层之一。本文通过收集截至2015年底150眼雾迷山组地热井的数据资料,计算得出区内雾迷山组热储在回灌条件下地热资源可采量为14.108×10~8 m~3,地热流体可采热量47.021×10~(16) J/a,折合标准煤1 604.814×10~4 t/a,并对雾迷山组热储层的地热流体热量开采系数、最大水位降速和地热流体热量潜力模数三个指标综合考虑,确定地热资源开发利用潜力,可为今后雾迷山组地热流体的勘查和开发利用提供参考。     

Method to characterize aquitards above leaky aquifers with water supply wells

Leaky aquifers provide protected drinking water since the aquifer is overlain by an aquitard, and this study develops a method to estimate hydraulic properties of the latter deposit. Steady pumping, supply well shutdowns, and slug tests generate data in adjacent monitoring well clusters that characterize the aquitard. An existing steady model estimates a site-averaged value of the aquitard permeability k if its thickness is known, and this site-averaged estimate may be compared with local k estimates from conventional and extended slug tests. A shutdown attenuation model estimates a local value of the consolidation coefficient C _V, which combines with the local k value to specify the compressibility α of the aquitard. The method is illustrated for the Fowl Meadow Aquifer, a stratified drift deposit used as a drinking water supply in eastern Massachusetts (USA), with an overlying silt aquitard of 10 m thickness. Steady data and theory suggest a site-averaged k of 2.3?×?10^–17?m² for the aquitard, while the shutdown attenuation model generates local C _V values that vary from 10^–5 to 10^–3?m²/s. The slug tests yield a local k variation (10^–17–10^–13?m²) that brackets the site-averaged value, and an α range of 10^–9–10^–7?Pa^–1.     

The use of O,H, B,Sr and S isotopes for tracing the origin of dissolved boron in groundwater in Central Macedonia,Greece

The groundwater B concentration in Mesozoic karst, Neogene and alluvial aquifers in the West part of Chalkidiki province in Central Macedonia, Greece reaches 6.45 mg L⁻¹, which exceeds the limit of 1 mg L⁻¹, set by the European Union for drinking water. The high B contents have been detected in this area, not only near the shoreline, where seawater intrusion occurs, but also in the inland part of the basin. Multi isotope (²H, ¹⁸O, ³⁴S, ¹⁸O_(SO4), ¹¹B, ⁸⁷Sr/⁸⁶Sr) data from borehole and thermal water springs allow identification of the possible B sources. The B dissolved in groundwater in the Chalkidiki area is mainly geogenic. The low δ¹¹B values, 0–1‰, similar to those of thermal fluids from continental geothermal fields, and the low Cl/B ratio compared to seawater both indicate a geothermal origin for B and reflect deep circulation and interaction with igneous rocks. The ⁸⁷Sr/⁸⁶Sr ratio also indicates that the deep-aquifer granodiorite is the predominant rock source of Sr, while the shallow limestone unit has negligible effects on the dissolved Sr budget in these thermal karst waters which O and H isotopes show to be of meteoric origin. The main source of high B in borehole water is mainly mixing with B-rich geothermal water. The mixing between geothermal water and water from the Neogene aquifer is also reflected by isotopic contents of SO₄.     

Groundwater contamination in parts of Nalgonda district,Telangana, India as revealed by trace elemental studies

The present paper deals with major and trace elements geochemistry of the groundwater from Nalgonda district, Telangana. The study area is very important in terms of anthropogenic activity like rapid industrial, urban development, pesticides, pharmaceutical, granite polishing and agro based industries. Inductively coupled plasma mass spectrometer (ICPMS) was employed to determine the concentration of trace elements in collected groundwater samples (bore well). These probe elements were further categorized as toxic elements (Pb, As, Cd, and V), alkaline earths (Sr and Ba), alkali metals (Li, Rb), transition metals (Cr, Mo and Ni), metallic elements (Cu, Fe, Zn, Al, Co), and other non-metallic elements (Se and Si). The groundwater quality was examined in perspective of Indian as well as World Health Organization drinking water standards. Based on the analytical results, groundwater in the study area is found to be slightly alkaline in nature and very hard, the average abundance of the major cations and anions is in the order of Ca⁺<Na⁺<Mg⁺<K⁺ and Cl^-<HCO₃ ^?<CO₃ ^?<SO₄ ^?<NO₃ ^?<F^– respectively. The dominant hydro chemical facies of groundwater is Na⁺ - HCO ₃ ^– – Cl^– and Na⁺ - Cl^– – HCO^– ₃ types.The results of trace elements shows that concentration of Pb, As, Cd, V in collected samples exceeding the desirable limits, and in the case of alkaline, alkali, transition, non-metallic elements, seventy per cent of the samples crossed the desirable limits, but all metallic elements viz. Cu, Fe, Zn, Al, Co is within the limits as per Indian as well as World Health Organizations drinking water standards. Factor analysis results shows that seven factors emerged as a significant contributor to the groundwater contamination is about 65.32 per cent. The spatial variation maps decipher trace elemental concentrations both geogenic and anthropogenic origin, by three zones i.e. ‘low’, ‘moderate’ and ‘high’ of the study area based on environment using Arc-GIS. High concentrations of trace elements are indicative of phenomenal rise in chemical composition and likely to have its origin from silicate weathering reactions and dissolution/precipitation processes supported by rainfall and anthropogenic activities, indiscriminate use of fertilizers/pesticides, and disposal of waste and sewage, release of reactive pollutants into the atmosphere by industries. Hence, this work is of immense societal benefit in terms of prevailing human health hazards in the study area with a direct relevance to such industrially populated regions elsewhere.     

Numerical investigation on the implications of spring temperature and discharge rate with respect to the geothermal background in a fault zone

Geothermal springs are some of the most obvious indicators of the existence of high-temperature geothermal resources in the subsurface. However, geothermal springs can also occur in areas of low average subsurface temperatures, which makes it difficult to assess exploitable zones. To address this problem, this study quantitatively analyzes the conditions associated with the formation of geothermal springs in fault zones, and numerically investigates the implications that outflow temperature and discharge rate from geothermal springs have on the geothermal background in the subsurface. It is concluded that the temperature of geothermal springs in fault zones is mainly controlled by the recharge rate from the country rock and the hydraulic conductivity in the fault damage zone. Importantly, the topography of the fault trace on the land surface plays an important role in determining the thermal temperature. In fault zones with a permeability higher than 1 mD and a lateral recharge rate from the country rock higher than 1 m³/day, convection plays a dominant role in the heat transport rather than thermal conduction. The geothermal springs do not necessarily occur in the place having an abnormal geothermal background (with the temperature at certain depth exceeding the temperature inferred by the global average continental geothermal gradient of 30 °C/km). Assuming a constant temperature (90 °C here, to represent a normal geothermal background in the subsurface at a depth of 3,000 m), the conditions required for the occurrence of geothermal springs were quantitatively determined.     

Fate and transport of ethanol-blended dissolved BTEX hydrocarbons: a quantitative tracing study of a sand tank experiment

To estimate the behavior of ethanol-blended dissolved BTEX hydrocarbons in groundwater, a quantitative tracing study instead of qualitative analysis was carried out by using a large sand tank, into which 2-L solution including bromide, ethanol and dissolved BTEX was injected under a controlled hydraulic condition. Mean residence time (MRT), pore volume swept by solute (V _p), retardation coefficient (R) and biodegradation rate constant (k) of injected solutes were estimated. Compared with bromide that was used as a conservative tracer, ethanol and BTEX had shorter MRT and smaller V _p with the sequence of EtOH < T < E < m/p-X < o-X < B < Br. Biodegradation was confirmed as evidenced by the consumptions of dissolved oxygen (DO), nitrate and sulfate, and the production of acetate. The sequence of k as EtOH > T > E > m/p-X > o-X > B was just opposite to the sequences of MRT and V _p. The relationship among above sequences implies that MRT and V _p can be used as indicators to assess in situ biodegradability of a solute. Biodegradation of a reactive solute can make its MRT shortened and V _p shrunk. In addition, the sorption of ethanol could be neglected (R = 1.0), whereas BTEX compounds were adsorbed (R = 1.04–1.15). It should be noted that biodegradation of a solute can affect the estimation of its retardation coefficient. To our knowledge, this paper provides an available route to quantitatively estimate biodegradability of a solute in groundwater.     

Hydro-geomechanical characterisation of a coastal urban aquifer using multiscalar time and frequency domain groundwater-level responses

Hydraulic properties of coastal, urban aquifers vary spatially and temporally with the complex dynamics of their hydrogeology and the heterogeneity of ocean-influenced hydraulic processes. Traditional aquifer characterisation methods are expensive, time-consuming and represent a snapshot in time. Tidal subsurface analysis (TSA) can passively characterise subsurface processes and establish hydro-geomechanical properties from groundwater head time-series but is typically applied to individual wells inland. Presented here, TSA is applied to a network of 116 groundwater boreholes to spatially characterise confinement and specific storage across a coastal aquifer at city-scale in Cardiff (UK) using a 23-year high-frequency time-series dataset. The dataset comprises Earth, atmospheric and oceanic signals, with the analysis conducted in the time domain, by calculating barometric response functions (BRFs), and in the frequency domain (TSA). By examining the damping and attenuation of groundwater response to ocean tides (OT) with distance from the coast/rivers, a multi-borehole comparison of TSA with BRF shows this combination of analyses facilitates disentangling the influence of tidal signals and estimation of spatially distributed aquifer properties for non-OT-influenced boreholes. The time-series analysed covers a period pre- and post-impoundment of Cardiff’s rivers by a barrage, revealing the consequent reduction in subsurface OT signal propagation post-construction. The results indicate that a much higher degree of confined conditions exist across the aquifer than previously thought (specific storage?=?2.3 × 10^?6 to 7.9 × 10^?5 m^?1), with implications for understanding aquifer recharge, and informing the best strategies for utilising groundwater and shallow geothermal resources.