| 大兴安岭南段道伦达坝铜多金属矿床流体包裹体研究和同位素特征 |
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| 引用本文： | 陈公正,武广,武文恒,张彤,李铁刚,刘瑞麟,武利文,章培春,江彪,王志利. 大兴安岭南段道伦达坝铜多金属矿床流体包裹体研究和同位素特征[J]. 地学前缘, 2018, 25(5): 202-221. DOI: 10.13745/j.esf.sf.2018.4.10 |
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| 作者姓名： | 陈公正 武广 武文恒 张彤 李铁刚 刘瑞麟 武利文 章培春 江彪 王志利 |
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| 作者单位： | 1. 中国地质大学(北京) 地球科学与资源学院, 北京 1000832. 中国地质科学院 矿产资源研究所 国土资源部成矿作用与资源评价重点实验室, 北京 1000373. Faculty of Science, University of Melbourne, Melbourne 3010, Victoria, Australia4. 内蒙古自治区地质调查院, 内蒙古 呼和浩特 0100205. 北京大学 造山带与地壳演化教育部重点实验室, 北京 100871 |
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| 基金项目： | 国家自然科学基金项目(41772086)；内蒙古自治区地质勘查基金项目(2015-01-YS01)；国家重点研发计划项目(2017YFC0601303) |
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| 摘 要： | 道伦达坝矿床位于大兴安岭南段，是一个中型的铜钨锡银矿床。矿体主要产于二叠系砂板岩中的断裂破碎带中，华力西期黑云母花岗岩中的断裂破碎带中亦赋存有矿体。该矿床的成矿过程可划分为4个阶段：石英萤石白云母电气石锡石黑钨矿阶段(Ⅰ阶段)、石英萤石黑钨矿黄铜矿毒砂磁黄铁矿阶段(Ⅱ阶段)、石英萤石黄铜矿黄铁矿磁黄铁矿银矿物阶段(Ⅲ阶段)和方解石萤石黄铁矿阶段(Ⅳ阶段)。道伦达坝矿床主要发育富液两相包裹体(WL型)、富气两相包裹体(WG型)和含子矿物多相包裹体(S型)。Ⅰ和Ⅱ阶段均发育WL型、WG型和S型包裹体，两阶段的均一温度和盐度分别介于309～389 ℃和242～339 ℃、6.2%～46.3% NaCleqv.和5.3%～41.4% NaCleqv.；Ⅲ阶段主要发育WL型和S型包裹体，均一温度介于153～268 ℃，盐度介于3.5%～35.4% NaCleqv.；Ⅳ阶段仅发育WL型包裹体，均一温度介于114～188 ℃，盐度介于2.1%～7.6% NaCleqv.。前两个阶段为中高温、高盐度流体，Ⅲ阶段流体具中低温、高盐度特征，而Ⅳ阶段为低温、低盐度流体。矿床的δ18OH2O值介于-10.0‰～7.2‰，δD值介于-127‰～-81‰，由Ⅰ阶段到Ⅳ阶段，成矿流体由以岩浆流体为主逐渐演化到以大气降水为主，表明道伦达坝矿床初始流体为岩浆热液，后期有大气降水的加入。硫同位素组成(-7.4‰～-1.2‰)表明成矿物质主要来自深源岩浆；铅同位素组成(μ值介于9.3～9.7)暗示成矿物质主要来自造山带物质部分熔融形成的岩浆。流体的多次沸腾和混合是矿质沉淀的主要机制。
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| 关 键 词： | 流体包裹体 H-O-S-Pb同位素 铜多金属矿床 道伦达坝 大兴安岭南段 |
| 收稿时间： | 2018-02-08 |
Fluid inclusion study and isotope characteristics of the Daolundaba copper-polymetallic deposit in the southern Great Xing an Range |
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| CHEN Gongzheng,WU Guang,WU Wenheng,ZHANG Tong,LI Tiegang,LIU Ruilin,WU Liwen,ZHANG Peichun,JIANG Biao,WANG Zhili. Fluid inclusion study and isotope characteristics of the Daolundaba copper-polymetallic deposit in the southern Great Xing an Range[J]. Earth Science Frontiers, 2018, 25(5): 202-221. DOI: 10.13745/j.esf.sf.2018.4.10 |
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| Authors: | CHEN Gongzheng WU Guang WU Wenheng ZHANG Tong LI Tiegang LIU Ruilin WU Liwen ZHANG Peichun JIANG Biao WANG Zhili |
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| Abstract: | The Daolundaba deposit in the southern Great Xingan Range, Inner Mongolia is a medium-sized copperwolframtinsilver deposit. Ore bodies are hosted in faulted and shattered zones and host rocks are mainly the Permian sandstone and slate with minor amounts of Variscan biotite granite. The mineralization process can be divided into four stages: quartzfluoritemuscovitetourmalinecassiteritewolframite (stage Ⅰ), quartzfluoritewolframitechalcopyritearsenopyritepyrrhotite (stage Ⅱ), quartzfluoritechalcopyritepyritepyrrhotitesilver-bearing mineral (stage Ⅲ), and calcitefluoritepyrite (stage Ⅳ) stages. In this study, three types of fluid inclusions (FIs) have been distinguished in quartz, fluorite, and calcite veins including liquid-rich (WL type), gas-rich (WG type), and daughter mineral-bearing (S type) inclusions. The FIs in both stages Ⅰ and Ⅱ were of WL-, WG-, and S-types, with homogenization temperatures and salinities varying from 309 to 389 ℃ and from 6.2 to 46.3 wt.% NaCleqv. in stage Ⅰ, respectively, and from 242 to 339 ℃ and from 5.3 to 41.4 wt.% NaCleqv. in stage Ⅱ, respectively. The FIs in stage Ⅲ contained mainly WL- and S-types, with homogenization temperatures and salinities ranging from 153 to 268 ℃ and from 3.5 to 35.4 wt.% NaCleqv., respectively. Only WL-type FIs occurred in stage Ⅳ, and the homogenization temperatures and salinities varied from 114 to 188 ℃ and from 2.1 to 7.6 wt.% NaCleqv., respectively. In general, the ore-forming fluids of stages Ⅰ/Ⅱ, Ⅲ and Ⅳ were characterized by moderatehigh temperature/high salinity, moderatelow temperature/high salinity and low temperature/low salinity fluids, respectively. The δ18OH2O and δD values of the ore-forming fluids were between -10.0‰ and 7.2‰, -127‰ and -81‰, respectively, demonstrating that, from the early to late stages, the ore-forming fluids of the Daolundaba deposit gradually evolved from magmatic fluids to mixtures of meteoric and magmatic waters. The δ34S values ranged from -7.4‰ to -1.2‰, indicating S came primarily from deep magma. The Pb isotopic composition (μ values 9.39.7) also indicated that Pb was mainly derived from the magma formed by partial melting of orogenic material. Thus, both S and Pb isotopic data suggest that the ore-forming materials originated mainly from magma. Overall, our study shows that the multi-stage boiling and mixing of the ore-forming magmatic fluids with meteoric water were the dominant mechanism for ore deposition. |
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| Keywords: | fluid inclusion H-O-S-Pb isotopes copper-polymetallic deposit Daolundaba southern Da Hinggan Ling |
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