| 氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲 |
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| 引用本文： | 林光西. 氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲[J]. 岩矿测试, 2008, 27(2): 151-152. |
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| 作者姓名： | 林光西 |
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| 作者单位： | 1.江苏省地质调查研究院,江苏南京210018 |
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| 基金项目： | 国土资源部地质调查项目 |
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| 摘 要： | 采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3 作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲.对测定介质、KBH4浓度、铁盐的作用等条件进行试验.方法检出限为0.0031μg/g,精密度(RSD,n=11)＜6.10%.方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致.
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| 关 键 词： | 氢化物发生 原子荧光光谱法 碲 地球化学样品 氢化物发生 原子 荧光光谱法 直接测定 地球化学样品 Hydride Tellurium Trace Determination 标准值 结果 地球化学标准物质 国家 方法检出限 精密度 试验 条件 作用 铁盐 浓度 |
| 文章编号： | 0254-5357(2008)02-0151-02 |
| 修稿时间： | 2007-08-10 |
Direct Determination of Trace Tellurium in Geochemical Samples by Hydride Generation-Atomic Fluoresence Spectrmetry |
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| Direct Determination of Trace Tellurium in Geochemical Samples by Hydride Generation-Atomic Fluoresence Spectrmetry[J]. Rock and Mineral Analysis, 2008, 27(2): 151-152. |
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| Authors: | LIN Guang-xi |
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| Affiliation: | LIN Guang-xi(Geological Survey of Jiangsu Province,Nanjing 210018,China) |
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| Abstract: | A method for the direct determination of tellurium in geochemical samples by hydride generation-atomic fluorescence spectrometry(HGAFS) was established.The sample was decomposed with mixed acid of HNO3-HF-HClO4.The instrumental parameters were optimized and the effect of some influencing factors such as HCl and KBH4 concentrations on Te determination were studied.The detection limit of the method for Te is 0.0031 μg/g.The method has been applied to the determination of trace tellurium in National Standard Reference Geochemical Materials and the results are in agreement with certified values with precision of less than 6.10%RSD(n=11). |
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| Keywords: | hydride generation atomic fluorescence spectrometry tellurium geochemical sample |
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