| 铁氧化物对土壤解吸阿特拉津的影响 |
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| 引用本文： | 石健,孙金超,周静珊,丁建东. 铁氧化物对土壤解吸阿特拉津的影响[J]. 地球科学, 2012, 37(2): 332-336. DOI: 10.3799/dqkx.2012.038 |
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| 作者姓名： | 石健 孙金超 周静珊 丁建东 |
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| 作者单位： | 南通大学化学化工学院, 江苏南通 226019 |
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| 基金项目： | 国家自然科学基金项目21177067江苏省自然科学基金重点项目BK2010034南通大学自然科学基金项目09zy004 |
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| 摘 要： | 阿特拉津是一种典型的环境激素, 铁氧化物是土壤矿物质的主要成分之一, 研究铁氧化物对阿特拉津的吸附行为有助于深入了解环境激素在环境中的行为.在研究阿特拉津的污染土壤与铁氧化物的混合物对阿特拉津吸附与解吸作用机理的基础上, 通过采用不同配比的土壤与铁氧化物的混合物对农药阿特拉津进行解吸行为过程的模拟, 并改变解吸时间、温度、pH值等因素, 研究影响解吸行为的主要因素.结果表明: 温度、pH值、铁氧化物与土壤的不同配比等因素均会对阿特拉津的解吸作用产生不同程度的影响.混合物对阿特拉津的解吸一般在4h左右便可达到动态平衡, 酸性或碱性环境以及适当的温度条件均会在一定程度上增强解吸作用, 且发现混合物比原土壤的解吸效果更明显.
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| 关 键 词： | 环境激素 铁氧化物 吸附/解吸 污染控制 环境工程 |
| 收稿时间： | 2010-08-20 |
Effect of Iron Oxide on the Desorption Characteristics of Atrazine in Soil |
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| Abstract: | Atrazine is a typical environmental hormone and iron oxide which is one of the major components in the soil minerals. Studying of iron oxide on the adsorption behavior of atrazine facilitates the understanding of acts of environmental hormones in the environment. In this paper, the effects of the atrazine polluted soil and mixture of iron oxides on the adsorption and desorption of atrazine is studied, and three different ratios of soil and a mixture of iron oxides on the atrazine desorption are investigated. In addition, the main factors are found by means of changing factors such as desorption time, temperature, and pH value. Results show that temperature, pH, ratio of iron oxides and soil all affect the desorption in different degrees. Dynamic equilibrium of the effect of the mixture on the desorption could be achieved in about 4 hours generally. Acid or alkaline environment and the appropriate temperature enhance the desorption, and the mixture obviously has better desorption effect than the original soil. |
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