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鄂尔多斯盆地深部富铀烃源岩提供铀源可能性的实验研究
引用本文:王苗,吴柏林,李艳青,刘池阳,郝欣,刘明义,张婉莹,李琪,姚璐航,张效瑞. 鄂尔多斯盆地深部富铀烃源岩提供铀源可能性的实验研究[J]. 地球科学, 2022, 47(1): 224-239. DOI: 10.3799/dqkx.2021.050
作者姓名:王苗  吴柏林  李艳青  刘池阳  郝欣  刘明义  张婉莹  李琪  姚璐航  张效瑞
作者单位:西北大学大陆动力学国家重点实验室, 陕西西安 710069
基金项目:中国地质调查局项目(Nos.12120115013501,12120114009201,DD20211550);辽河油田公司科技项目(No.2021JK-07-3);国家基础科学人才培养基金项目(No.XDCX2020-08)。
摘    要:鄂尔多斯盆地上三叠统延长组长7段石油优质烃源岩以富铀为特色,而盆地侏罗?白垩纪地层以赋存大量砂岩型铀矿而著称.为探索深部长7富铀烃源岩为浅部砂岩型铀矿形成提供铀源的可能性,选择盆地南部的富铀烃源岩、油样以及具有代表性的碳酸铀酰作为反应物,在中?高温高压还原条件下分别进行烃源岩生排烃?排铀模拟实验和油?铀关系模拟实验.结...

关 键 词:鄂尔多斯盆地  富铀烃源岩  砂岩型铀矿  模拟实验  铀源  铀迁移形式  矿床学
收稿时间:2021-01-04

Experimental Study on Possibility of Deep Uranium-Rich Source Rocks Providing Uranium Source in Ordos Basin
Wang Miao,Wu Bailin,Li Yanqing,Liu Chiyang,Hao Xin,Liu Mingyi,Zhang Wanying,Li Qi,Yao Luhang,Zhang Xiaorui. Experimental Study on Possibility of Deep Uranium-Rich Source Rocks Providing Uranium Source in Ordos Basin[J]. Earth Science-Journal of China University of Geosciences, 2022, 47(1): 224-239. DOI: 10.3799/dqkx.2021.050
Authors:Wang Miao  Wu Bailin  Li Yanqing  Liu Chiyang  Hao Xin  Liu Mingyi  Zhang Wanying  Li Qi  Yao Luhang  Zhang Xiaorui
Affiliation:(State Key Laboratory of Continental Dynamics,Northwest University,Xi’an 710069,China)
Abstract:The high quality source rocks of the Chang 7 Member in Yanchang Formation of the Upper Triassic in the Ordos Basin are characterized by uranium enrichment,while the Jurassic-Cretaceous strata of the basin are famous for hosting a large number of sandstone-type uranium deposits.To analyze the possibility of source rocks providing uranium source for shallow sandstone type uranium deposits,the uranium-rich source rocks,oil samples from the Chang 7 Member and representative uranyl carbonate were selected as reactants,and simulation experiments of hydrocarbon generation and expulsion of uranium from source rocks and oil-uranium relationship were carried out respectively under the reduction conditions of medium-high temperature and high pressure.The results show that uranium can be discharged along with the process of hydrocarbon expulsion from source rock,and the increase of temperature and pressure at 30-200℃and 2-5 MPa is conductive to the increase of hydrocarbon generation and uranium discharge.The discharged rate of uranium increases with the increase of hydrocarbon generation and is generally 55%-75%.Among them,the proportion of soluble uranium from itself is about 12%,and the discharged rate of uranium caused by the superposition of hydrocarbon generation is 43%-48%.The uranium migration forms found in this experiment are special,such as tetravalent(UO2),hexavalent(UO3),mixed valence(U3O8)and hydrate colloid form(UO3·H2O,U6O7(OH)2O),which are mainly adsorbed by low-temperature oil-gas fluid,and the uranium adsorption capacity shows an increasing trend with the increase of temperature and the decrease of pressure.Thus,it is beneficial for uranium ore formation when low temperature uranium-bearing oil-hydrothermal fluids migrate to shallow strata.Based on the above analyses,it is considered that the source rocks of Chang 7 Member in the southern Ordos Basin can release or discharge a large amount of uranium,which can be adsorbed by low-temperature oil-gas in the form of tetravalent,hexavalent and mixed valence.Subsequently,the adsorbed uranium moves upwards along with the oil-water fluid through the fracture,providing partial material source for the formation of shallow sandstone-type uranium deposits of the basin.
Keywords:Ordos Basin  uranium-rich source rock  sandstone-type uranium deposit  simulation experiment  uranium source  uranium migration form  mineral deposit
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