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A NEW BIOGENIC SULFIDE CHEMICAL SENSOR FOR MARINE ENVIRONMENTAL MONITORING AND SURVEY
作者姓名:宋金明  赵卫东
作者单位:Institute of Oceanology,Chinese Academy of Sciences,Qingdao 266071,China
基金项目:ContributionNo.3 84 0fromtheInstituteofOceanology,ChineseAcademyofSciences.ProjectsupportedbytheNationalScienceFoundationforOut
摘    要:INTRODUCTIONBiogenicsulfideproducedbybacterialsulfatereductionisoneofthemostimportantindicatorsinanoxicmarineenvironments,particularlyinconfiningbays,pollutedestuariesandaquaculturear eas.Theincreaseofitsconcentrationusuallyindicatesworsenedconditions.…

关 键 词:化学传感器  硫化物  海洋监测  海洋调查
收稿时间:27 October 1999
修稿时间:16 August 2000

A new biogenic sulfide chemical sensor for marine environmental monitoring and survey
Song Jin-ming,Zhao Wei-dong.A NEW BIOGENIC SULFIDE CHEMICAL SENSOR FOR MARINE ENVIRONMENTAL MONITORING AND SURVEY[J].Chinese Journal of Oceanology and Limnology,2001,19(3):282-286.
Authors:Song Jin-ming  Zhao Wei-dong
Institution:(1) Institute of Oceanology, Chinese Academy of Sciences, 266071 Qingdao, China
Abstract:A new convenient sulfide electrochemical sensor for marine environmental in situ monitoring and real time survey was developed. The new sensor based on a solid Ag 2S membrane electrode has outstanding chemical sensitivity and stability. It responds to the activity of sulfide ions according to a Nernstian slope of -31mV/decade. The sensor can be used to determine the total concentration of sulfides ( C T) by calibrating the pH value of the solution to a standard pH. The practical measurement range for total sulfide concentration is 0.1-10 mg/L in seawater. The sensor has a very low potential drift (<4mV) during two months in 0.1 mg/L sulfide seawater. This paper describes the preparation of the sensitive membrane and some main properties of the sensor.
Keywords:sulfide    chemical sensor    marine monitoring and survey
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