An Experimental Study on Picromerite Equilkibrium in the Five—Component Brine System K—Na—Mg—Cl—SO4—H2O |
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引用本文: | 谷树起,郭志强,等.An Experimental Study on Picromerite Equilkibrium in the Five—Component Brine System K—Na—Mg—Cl—SO4—H2O[J].中国地球化学学报,1991,10(3):232-243,T001,T002. |
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作者姓名: | 谷树起 郭志强 |
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作者单位: | GeologicalInstituteforChemicalMinerals,MinistyofChemicalIndustry |
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摘 要: | This paper presents the results of experiments on the physicochemical conditions for the formation of picaromerite in the five-component brine system K-Na-Mg-Cl-SO4-H2O and the process of isothermal evaporation-crystallization of picromerite from brines.The metastable phase fields of picromerite at 15,10 and 5℃and its stable equilibrium phase field at -5℃ have been established.In addition,the phase equilibrium relationships have also been established for other salt minerals.The lower limit of formation temperature of picromerite has been deduced on the basis of experi-mental results.The isothermal evaporation crystallization path of the invariant assemblage(point D) of picromerite,epsomite,sylvite and halite at 25,15,10 and 5℃ has been revealed.Furthermore,some controversial problems are approached concerning the 25℃“solar” diagram and the 25℃ metastable phase diagram of this system.
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关 键 词: | 物理化学性质 稳定性 温度 软钾镁钒 钾-钠-镁-氧-硫硫根离子水盐体系 |
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