| 高岭石—聚丙烯腈夹层复合物的制备 |
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| 引用本文： | 厦华,佟健,侯常娥.高岭石—聚丙烯腈夹层复合物的制备[J].矿物岩石,2001,21(4):7-10. |
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| 作者姓名： | 厦华 佟健 侯常娥 |
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| 作者单位： | 1. 中国地质大学材料科学与化学工程学院
2. 中国地质大学材料科学与化学工程学院, |
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| 摘 要： | 作者通过XRD和IR等手段研究了高岭石－聚丙烯腈夹层复合物的形成过程。通过对高岭石／DMSO（二甲亚砜）、高岭石／乙酸铵等中间复合物的置换反应，成功地将丙烯腈单体引入高岭石层间。XRD谱表明高岭石层间被插入有机分子后，其层间距增大；IR谱显示有机分子与高岭石的外羟基可能以氢键的形式相互作用。在有引发剂的存在下，实现了丙烯腈单体在高岭石层间的聚合。
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| 关 键 词： | 夹层复合物 高岭石 聚丙烯腈 |
| 文章编号： | 1001-6872(2001)04-0007-04 |
PREPARATION OF A KAOLINITE-POLYACRYLONITRILE INTERCALATION COMPOUND |
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| XIA Hua TONG Jian HOU Chang-e Institute of Material Science and Chemical Engineering,China University of Geoscience,Wuhan.PREPARATION OF A KAOLINITE-POLYACRYLONITRILE INTERCALATION COMPOUND[J].Journal of Mineralogy and Petrology,2001,21(4):7-10. |
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| Authors: | XIA Hua TONG Jian HOU Chang-e Institute of Material Science and Chemical Engineering China University of Geoscience Wuhan |
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| Institution: | XIA Hua TONG Jian HOU Chang-e Institute of Material Science and Chemical Engineering,China University of Geoscience,Wuhan 430074 |
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| Abstract: | The intercalation complex involving the layer silicate kaolinite and organic compound is studied through the application of infrared absorption spectroscopy and X-ray powder diffraction.The acrylonitrile can be intercalated between the layers of kaolinite by displacing intercalated ammonium acetate from kaolinite/ammonium acetate complex.The XRD pattern showed that the layer interval of kaolinite increased.The IR spectra provide evidence that the inner-surface hydroxyl groups of kaolinite are hydrogen bonded to intercalated DMSO molecules.When there is a initiator,the acrylonitrile monomer can be polymerized between the layers. |
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| Keywords: | kaolinite intercalation complex polyacrylonitrile |
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