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我国几种常见润滑油的指纹分析
引用本文:刘 星,王 震,马新东,丁 丽,徐恒振,姚子伟.我国几种常见润滑油的指纹分析[J].海洋科学,2011,35(6):39-43.
作者姓名:刘 星  王 震  马新东  丁 丽  徐恒振  姚子伟
作者单位:国家海洋环境监测中心,中国海监检验鉴定标准实验室,辽宁大连116023
基金项目:海洋公益性项目(201005034)
摘    要:采用气相色谱/质谱方法(GC/MS)对7种常见润滑油中的生物标志化合物(正构烷烃、姥鲛烷、植烷、甾烷、萜烷、多环芳烃)进行定性分析,并基于其生物标志化舍物指纹信息进行了多元统计分析。结果表明,润滑油的气相色谱图中不可分辨的混合物(UCM)具有明显优势;润滑油中含有丰富的甾、萜烷类稠环生物标志化合物,仅含有非常少量的饱和...

关 键 词:润滑油  生物标志化合物  溢油鉴别  主成分分析  聚类分析
收稿时间:2010/6/26 0:00:00
修稿时间:2010/9/14 0:00:00

Fingerprints analysis of the lubricating oils produced in China
LIU Xing,WANG Zhen,MA Xin-dong,DING Li,XU Heng-zhen,YAO Zi-wei.Fingerprints analysis of the lubricating oils produced in China[J].Marine Sciences,2011,35(6):39-43.
Authors:LIU Xing  WANG Zhen  MA Xin-dong  DING Li  XU Heng-zhen  YAO Zi-wei
Institution:LIU Xing,WANG Zhen,MA Xin-dong,DING Li,XU Heng-zhen,YAO Zi-wei(National Marine Environmental Monitoring Center,Inspection & Authentication Standard Lab of China Ma-rine Surveillance,Dalian 116023,China)
Abstract:Fingerprint compounds (alkanes, pristine, phytane, sterids, terpanes and polycyclic aromatic hydrocarbons) in seven lubricating oils produced in China were quantitatively analyzed using gas chromatography/mass spectrometry (GC/MS). Multivariate statistical analysis was done based on fingerprints information. The result showed that the unresolved complex mixture (UCM) had obvious predominance in gas chromatogram of lubricating oils. The sterids and terpanes were rich in lubricating oils, but the paraffinic hydrocarbons (alkanes, pristine, phytane) and PAHs (PAHs homologues, alkylated PAHs homologues, dibenzothiophene series) were of low contents in lubricating oils; The results of principal component analysis (PCA) and cluster analysis based on the fingerprints information were same and both could be used for lubricating oils identification.
Keywords:lubricating oils  biomarker  oil spill identification  principal component analysis (PCA)  clustering analysis
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