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LiPF6的水解行为研究
引用本文:曹晓燕,李苓,王佳,熊俊威,孙淑红,刘海胜.LiPF6的水解行为研究[J].中国海洋大学学报(自然科学版),2005,35(6):1026-1028.
作者姓名:曹晓燕  李苓  王佳  熊俊威  孙淑红  刘海胜
作者单位:1. 中国海洋大学化学化工学院,山东,青岛,266003
2. 中国海洋大学化学化工学院,山东,青岛,266003;青岛澳柯玛新能源技术有限公司,山东,青岛,266555
3. 青岛澳柯玛新能源技术有限公司,山东,青岛,266555
摘    要:利用直接电位法,采用标准加入的方式测定了不同浓度和温度条件下,LiPF6水溶液中的F-浓度,同时考察了碱处理对LiPF6水解的影响,并采用电导率测定结果进行了验证.实验表明,LiPF6能够在水中稳定存在,且几乎不受碱度和温度的影响.

关 键 词:LiPF6  水解  直接电位法
文章编号:1672-5174(2005)06-1026-03
收稿时间:2005-04-28
修稿时间:2005-07-04

A Study on the Hydrolysis of LiPF6
CAO Xiao-Yan,LI Ling,WANG Jia,XIONG Jun-Wei,SUN Shu-Hong,LIu Hai-Sheng.A Study on the Hydrolysis of LiPF6[J].Periodical of Ocean University of China,2005,35(6):1026-1028.
Authors:CAO Xiao-Yan  LI Ling  WANG Jia  XIONG Jun-Wei  SUN Shu-Hong  LIu Hai-Sheng
Institution:1. College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266003, China; 2. Qingdao Aucma New Power Technology Co., Ltd., Qingdao 266555, China
Abstract:LiPF6 hydrolysis was studied and the results are presented in the present paper. The contents of F^- in LiPF6 solutions under different conditions were determined by potential measurements. It was found that PF6 - is stable in water. The concentration, temperature and the basic solvent have little effects on the hydrolysis. The effects were also investigated by means of conductivity measurement.
Keywords:LiPF6  hydrolysis  potential measurement
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