东海陆架盆地西湖凹陷南部花港组砂岩储层成岩流体演化特征：来自岩石、矿物及同位素地球化学的约束

渐新世花港组是东海陆架盆地西湖凹陷发育的最主要储层，基于普通薄片、铸体薄片、扫描电镜和荧光显微观察，结合同位素地球化学对东海陆架盆地西湖凹陷花港组砂岩储层的成岩作用、成岩序列及成岩流体演化进行了研究。结果表明，花港组砂岩储层目前处于中成岩阶段B期，主要经历了机械压实、绿泥石粘土摸、酸性及碱性溶蚀作用，石英次生加大，碳酸盐胶结和自生高岭石胶结等成岩作用。研究区发育有三期碳酸盐胶结物，早期菱铁矿胶结物，中期铁方解石和晚期铁白云石。根据碳酸盐胶结物的碳氧同位素特征分析认为早期碳酸盐胶结物是由过饱和的碱性湖水沉淀造成的，而晚期碳酸盐胶结物的形成与有机酸密切相关。研究区存在两类溶蚀作用，酸性溶蚀作用和碱性溶蚀作用，早期的酸性溶蚀作用主要是有机酸对长石、岩屑及早期碳酸盐胶结物的溶蚀，晚期的碱性溶蚀作用主要是发生于碱性环境下流体对石英及硅质胶结物的溶蚀。研究区发育有两期油气充注，早期发生于晚中新世，早期发生于晚中新世，早于中期碳酸盐胶结，晚于长石溶蚀和石英胶结充注，充注量较大，第四纪以来研究区发生了第二次充注，第二次充注发生于铁白云石胶结之后，此时储层已非常致密。

Diagenetic fluids evolution of Oligocene Huagang Formation sandstone reservoir in the south of Xihu Sag, the East China Sea Shelf Basin: constraints from petrology, mineralogy, and isotope geochemistry

The Oligocene Huagang Formation is the main sandstone reservoir in the Xihu Sag, situated in the east of the East China Sea Shelf Basin. With an integrated approach of thin-section petrography, ultra-violet fluorescence microscopy, scanning electron microscopy, and isotope geochemistry, the different diagenetic features were identified, the typical diagenetic parasequences were established, and the diagenetic fluids evolution history were reconstructed for the Oligocene Huagang Formation sandstone reservoir in the south of Xihu Sag. The Huagang Formation sandstone reservoir is now in Period B of the mesodiagenesis, which has undergone significant diagenetic alterations such as mechanical compaction, Pore-lining chlorite cement, feldspar dissolution, quartz cementation and dissolution, and carbonate cementation. Three types of carbonate cements (early siderite, medium ferrocalcite and late ankerite) were identified in the Huagang Formation sandstone reservoir. The carbon and oxygen isotopic compositions of carbonate cements show that the early calcite precipitate from alkaline lacustrine environment whereas the late carbonate cements were closely related to the organic acids. To the Huagang Formation sandstone reservoir, it has experienced two main episodes of dissolution during diagenesis. The early dissolution is that unstable components such as feldspar, lithic fragments, and carbonate cement were dissolved by acidic water. The second dissolution is that quartz and other silicate minerals were dissolved under the alkaline condition. Two main phases of hydrocarbon charging occurred in this study area. The first hydrocarbon emplacement was prior to the medium carbonate cementation but posterior to feldspar dissolution and the onset of quartz cementation at the end of the Miocene. The second hydrocarbon charging occurred in the Quaternary period after the late carbonate precipitation.