Ore Genesis for Stratiform Ore Bodies of the Dongfengnanshan Copper Polymetallic Deposit in the Yanbian Area, NE China:Constraints from LA-ICP-MS
in situ Trace Elements and Sulfide S–Pb Isotopes |
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作者姓名: | LU Siyu REN Yunsheng YANG Qun SUN Zhenming HAO Yujie SUN Xinhao |
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作者单位: | 1 College of Earth Sciences, Jilin University, Changchun 130061, China,1 College of Earth Sciences, Jilin University, Changchun 130061, China;2 Institute of Disaster Prevention, Beijing 101601, China,1 College of Earth Sciences, Jilin University, Changchun 130061, China,1 College of Earth Sciences, Jilin University, Changchun 130061, China,1 College of Earth Sciences, Jilin University, Changchun 130061, China;3 Key Laboratory of Mineral Resources Evaluation in Northeast Asia, Ministry of Natural Resources of China, Changchun 130061, China and 1 College of Earth Sciences, Jilin University, Changchun 130061, China |
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基金项目: | This study is supported by the National Natural Science Foundation of China |
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摘 要: | The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks.
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关 键 词: | LA-ICP-MS in situ trace element S–Pb isotope VMS-type stratiform orebodies Dongfengnanshan copper polymetallic deposit Tianbaoshan ore district |
收稿时间: | 2019/5/15 0:00:00 |
修稿时间: | 2019/8/14 0:00:00 |
Ore Genesis for Stratiform Ore Bodies of the Dongfengnanshan Copper Polymetallic Deposit in the Yanbian Area,NE China: Constraints from LA‐ICP‐MS in situ Trace Elements and Sulfide S–Pb Isotopes |
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Authors: | LU Siyu REN Yunsheng YANG Qun SUN Zhenming HAO Yujie and SUN Xinhao |
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Abstract: | The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast (NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and vein‐type ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and vein‐type ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley‐type (MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic‐associated massive sulfide (VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS‐type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS‐type deposits. These characteristics also reflect the intermediate ore‐forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS‐type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed‐source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMS‐type deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS‐type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks. |
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Keywords: | LA‐ICP‐MS in situ trace element S–Pb isotope VMS‐type stratiform orebodies Dongfengnanshan copper polymetallic deposit Tianbaoshan ore district |
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