Stable isotope(δ~(13)C_(ker),δ~(13)C_(carb),δ~(18)O_(carb)) distribution along a Cambrian outcrop section in the eastern Tarim Basin,NW China and its geochemical significance |
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摘 要: | This study investigated the geochemical features of the lower Paleozoic strata of Yaerdang Mountain outcrop along with the core samples from well TD2∈ in the eastern Tarim Basin,NW China.The total organic carbon abundance,hydrocarbon-generating precursor biospecies,and stable isotope ratios of organics and carbonate(δ~(13)C_(ker),δ~(13)C_(carb) and δ~(18)O_(carb)) were comprehensively studied for their possible correlative constraints during sedimentary evolution.The results revealed that the δ~(13)C_(ker)(VPDB) of Cambrian kerogens along the outcrop section varied from-34.6‰ to-28.4‰,indicating an increasing tendency from the lower Cambrian to the upper Cambrian.This was on the whole accompanied by the variation in the δ~(13)C_(carb) and δ~(18)O_(carb) along the profile,which might be associated with the changes in the sea level and also in the compositional variation of benthic and planktonic biomass.The large variation in the stable carbon isotope ratios up to 6‰ along the outcrop section reflected the heterogeneity of the Cambrian source rocks from the eastern Tarim Basin.Hence,the ~(13)C-enriched crude oils from well TD2∈might have been derived from a localized stratum of Cambrian source rocks.The results from this study showed the possibility of multiple source kitchens in the Cambrian-lower Ordovician portion of Tarim Basin.
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收稿时间: | 4 June 2015 |
Stable isotope (δ13Cker, δ13Ccarb, δ18Ocarb) distribution along a Cambrian outcrop section in the eastern Tarim Basin,NW China and its geochemical significance |
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Authors: | Hu Liu Zewen Liao Haizu Zhang Yankuan Tian Bin Cheng Shan Yang |
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Institution: | 1. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;2. Sichuan Key Laboratory of Shale Gas Evaluation and Exploitation, Chengdu 610091, China;3. Research Institute of Petroleum Exploration and Development, PetroChina Tarim Oilfield Company, Korla 841000, Xinjiang, China |
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Abstract: | This study investigated the geochemical features of the lower Paleozoic strata of Yaerdang Mountain outcrop along with the core samples from well TD2∈ in the eastern Tarim Basin, NW China. The total organic carbon abundance, hydrocarbon-generating precursor biospecies, and stable isotope ratios of organics and carbonate (δ13Cker, δ13Ccarb and δ18Ocarb) were comprehensively studied for their possible correlative constraints during sedimentary evolution. The results revealed that the δ13Cker (VPDB) of Cambrian kerogens along the outcrop section varied from ?34.6‰ to ?28.4‰, indicating an increasing tendency from the lower Cambrian to the upper Cambrian. This was on the whole accompanied by the variation in the δ13Ccarb and δ18Ocarb along the profile, which might be associated with the changes in the sea level and also in the compositional variation of benthic and planktonic biomass. The large variation in the stable carbon isotope ratios up to 6‰ along the outcrop section reflected the heterogeneity of the Cambrian source rocks from the eastern Tarim Basin. Hence, the 13C-enriched crude oils from well TD2∈ might have been derived from a localized stratum of Cambrian source rocks. The results from this study showed the possibility of multiple source kitchens in the Cambrian–lower Ordovician portion of Tarim Basin. |
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Keywords: | Kerogen Heterogeneity Tarim Basin Stable isotope geochemistry |
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