A lithogeochemical approach to Stratigraphical problems at the Millstream potash deposit, New Brunswick, Canada

A lithogeochemical study was undertaken of the Millstream potash deposit, New Brunswick, Canada, a marine evaporite deposit with a complex depositional and tectonic history. The objective of the study was to determine if potash intersections in boreholes represent different geological horizons, or the same stratum repeated by folding or faulting. The deposit is found at a depth of 800–1000 m.Water-soluble and -insoluble fractions of drill core from five ore zones in four holes were analyzed using multielement ICP instrumentation following sequential hot water and aqua regia leaches. Meaningful variations in the data for the different ore zones were evident for eight elements in the water-soluble portion, and for seventeen elements in the water-insoluble residue. These results characterize a lowermost sylvinite unit which is relatively depleted in most elements, with the exception of Mg and Al in the residue. Regression analysis indicates a weak correlation between Fe and the common base metals, in contrast to the immediately overlying sylvinite unit which is relatively enriched in most elements, including Fe, but where Fe apparently exerts no control over the base metals. Cluster analysis confirms these two units are easily distinguished from each other. The upper two ore horizons are distinguishable from the lower units on the basis of different abundances of some elements, such as water-soluble B, and on the strong scavenging abilities of Fe on the common base metals.No single element is able to uniquely fingerprint a particular sylvinite horizon, but suites of elements are able to classify each horizon as geochemically distinctive. The results appear to confirm the validity of the geological correlations.