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几个与温度有关的平衡关系式的简便推导
引用本文:方裕勋,罗新.几个与温度有关的平衡关系式的简便推导[J].华东地质学院学报,1997(2).
作者姓名:方裕勋  罗新
作者单位:华东地质学院应用化学系
摘    要:本文讨论了几个温度影响平衡的关系式,认为应用杂平衡常数的概念,可以把它们归结为温度对平衡常数的影响,从而使有关公式的推导更简捷明快。并从动力学和统计热力学的角度,推导出温度对平衡常数影响的关系式,指出上述影响的根源是温度影响粒子在能级中的玻兹曼分布

关 键 词:平衡常数  温度  玻兹曼分布

Several Relations of Temperature Effects on Equilibrium
Fang Yuxun\,Luo Xin.Several Relations of Temperature Effects on Equilibrium[J].Journal of East China Geological Institute,1997(2).
Authors:Fang Yuxun\  Luo Xin
Abstract:The paper discusses several relations of temperature effects on equilibrium comes to the conclusion that by use of complex equilibrium constant the temperature effects on equilibrium can be due to the temperature effects on equilibrium constant and the derivation of the equations can be simplified greatly.The equations can also be derived from chemical dynamics and statistical thermodynamicx .The reasons of temperature effects are the particle's .The reasons of temperature effects are the particle's Boltzmann distrition on energy level.
Keywords:equilibrium value  temperature  Boltzmann distribution  
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