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Measurement of Labile Cu, Pb and Their Complexation Capacity in Yueqing Bay in Zhejiang Province, China
作者姓名:王正方  吕海燕  傅和芳
作者单位:Second Institue of Oceanography,State Oceanography Administration,Second Institue of Oceanography,State Oceanography Administration,Second Institue of Oceanography,State Oceanography Administration Hangzhou 310012,China,Hangzhou 310012,China,Hangzhou 310012,China
基金项目:ProjectNo .40 0 760 2 5supportedbytheNSFC .
摘    要:1 INTRODUCTIONRecently ,thepollutionoftracemetalinseawaterhasbecomeincreasinglyevident.Researchershavefo cusedattentiontotracemetalpresentinvariousexistenceforms ,especiallyorganiccomplexingphases.Theexistencestatesandtransportmechanismofbaytracemetalswerethesubjectofstudybysomere searchers(Gu ,1 991 ;Florence ,1 998;Guo ,1 998;Wells,1 991 ,1 998a ,b ;Wellsetal.,1 998) .Whetherinfreshwaterorseawater,colloidsareclearlydominantfactorsaffectingtheexistencestatesandtransportmechanismoftrac…

关 键 词:测量      络合
收稿时间:17 September 2002
修稿时间:9 July 2003

Measurement of labile Cu,Pb and their complexation capacity in Yueqing Bay in Zhejiang Province,China
Wang?Zhengfang,Lu?Haiyan,Fu?Hefang.Measurement of Labile Cu, Pb and Their Complexation Capacity in Yueqing Bay in Zhejiang Province, China[J].Chinese Journal of Oceanology and Limnology,2004,22(1):64-69.
Authors:Wang Zhengfang  Lu Haiyan  Fu Hefang
Institution:(1) Second Institue of Oceanography, State Oceanography Administration, 310012 Hangzhou, China
Abstract:The complexation capacity of Cu and Pb and their labile and organic contents were determined separately for surface seawater samples from Yueqing Bay. The samples were prepared using Nuclepore filtration method yielding <1.0 μ, <0.4μm and <0.2μm particulate water samples. Our data indicated that the <0.2μm colloidal fraction is a major carrier for distribution of copper in seawater. Affinity of Cu to marine microparticles plays an important role in the process. Pb however, tends to be absorbed by >0.2μm particles. The complexation capacity of Pb with <0.2μm particulates was smaller than that with 0.2–1.0μm particulates, and averaged 11.5 and 23.0nmol/L respectively. The results suggested that colloidal particles were responsible for the distribution and concentration of Pb in seawater. Project No. 40076025 supported by the NSFC.
Keywords:colloidal particles  labile state  complexation capacity  trace metals  Yueqing Bay
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