Temporal Evolution of Boron Flux in the NE Japan and Izu Arcs Measured by Ion Microprobe from the Forearc Tephra Record

The enrichment of boron relative to similarly incompatible elements,such as Be, in arc volcanic rocks has been used as a proxy forthe involvement of slab flux in petrogenesis. New ion microprobeanalyses of single glass shards in tephra layers recovered bythe Ocean Drilling Program (ODP) in the Izu and NE Japan forearcbasins now allow the temporal variation in slab flux to be chartedsince 7 and 5 Ma, respectively. B/Be ratios are typically <70in NE Japan and <130 in Izu, with no single grain exceeding200. Although moderate to high for modern arcs, these valuesare much less than those recorded in the Marianas and Tongaat 3–4 Ma, shortly after the start of rifting of theirback-arc basins. This observation suggests that the peak B/Bevalues seen in Tonga and the Marianas are related to the tectonicsof slab roll-back and basin opening, rather than changes inthe dynamics of the Pacific Plate. There is no temporal trendto enrichment in the high field strength elements (HFSE) orrare earth elements (REE) in either Izu or NE Japan since 7Ma, although the two elemental groups do show clear positivecorrelation. A lack of correlation between REE, HFSE and B/Besuggests that slab flux is not the only control on melting inthese arcs.