Theory of metamorphic segregation and related processes

Metamorphic segregation is defined here as the formation and growth of bands or domains of different bulk compositions within an originally unbanded rock. It can result from an instability arising in some deforming rocks when diffusion transfer is significant. The nature of this instability is demonstrated separately for a differentiation associated with a crenulation (Type C) and for one without crenulation (Type L). However, the continuous gradation between the two types observed in nature is also expected from the models.A requirement for both types is that one chemical component of the rock, typically silica, diffuse more rapidly than others, e.g. phyllosilicate components, in response to stress-induced pressure gradients. In addition, Type L requires that, at least at an early stage, portions of the rock rich in this mobile component, e.g. rich in quartz, be more competent than those portions which are poor in quartz. By a process akin to the development of pressure shadows, silica diffuses toward domains which are already the richest in quartz. Alternatively, if the rock is chemically open to loss of silica, this silica preferentially originates from dissolution of quartz in the more mica-rich domains. In either case the compositional contrast between domains is increased and metamorphic segregation results. Type C differentiation is best explained if we accept the suggestion made by many petrographers that layer silicates catalyse the pressure-induced transfer of silica. This suggestion can in fact account for other features of metamorphic segregation bands.Metamorphic segregation should also proceed during the development of quartz segregations, quartz rods, slaty cleavage and mylonite banding. The stress distribution argued for Type L bands may also occur in many banded migmatites. In migmatites. however, the assemblage crystallizing in the leucosome may be derived from a circulating hydrothermal fluid as well as from diffusion transfer.