Therm odynamics of Diagenetic Fluid and Fluid／Mineral Reactions in the Eogene Xingouzui Formation,Oil Field T,Jianghan Basin

Thermodynamics of diagenetic fluid and fluid/mineral reactions in the Eogene Xingouzui Formation,oil Field T,Jianghan Basin

This study focuses on the thermodynamics of diagenetic fluid from the Eogene Xingouzui Formation which represents the most important reservoir in Field Oil T in the Jianghan Basin. The measured homogenization temperatures (110–139 °C) of fluid inclusions in diagenetic minerals fell within the range of 67 –155 °C at the middle diagenetic stage. The pressure of diagenetic fluid is estimated at 10.2 –56 MPa. The activity of ions in the fluid shows a tendency of Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ > Fe³⁺ > Fe²⁺ for cations, and HCO ₃ ⁻ > SO ₄ ²⁻ > F⁻ > Cl⁻ > CO ₃ ²⁻ for anions. For the gaseous facies, there is a tendency of CO₂> CO> H₂S> CH₄> H₂. According to the thermodynamic calculations, the pH and Eh of the fluid are 5.86–6.47 and −0.73–−0.64V, respectively. As a result of the interaction between such a diagenetic fluid and minerals in the sediments, feldspars were dissolved or alterated by other minerals. The clay mineral kaolinite was instable and hence was replaced by illite and chloritoid. This project was jointly funded by the National Natural Science Foundation of China (49133080) and the Open Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences.