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油页岩灰渣制备人造大理石及其性能
引用本文:甘树才,杨春明,徐吉静,来雅文,李广环,肖国拾.油页岩灰渣制备人造大理石及其性能[J].吉林大学学报(地球科学版),2011,41(3):879-884.
作者姓名:甘树才  杨春明  徐吉静  来雅文  李广环  肖国拾
作者单位:1.吉林大学化学学院,长春130026;2.吉林大学地球探测科学与技术学院,长春130026; 3.吉林大学测试科学实验中心,长春130026
基金项目:国家“863”计划项目(2007AA06Z202); 国家科技重大专项(2008ZX05018-005)
摘    要:利用油页岩灰渣、不饱和聚酯树脂为主要原料,辅助加入固化剂和促进剂,室温固化合成一种新型人造大理石装饰材料。运用实验系统研究原料配比、固化剂和促进剂用量、固化时间、树脂类型与填料粒度等因素对材料性能的影响,并确定了大理石制备的最佳配方。基层最佳配方(质量分数):不饱和树脂1号为20%~27%、引发剂0.5%~2.25%、促进剂0.5%~1.5%、油页岩灰渣50%~70%、碳酸钙粉5%~20%;表层最佳配方(质量分数):不饱和树脂1号为25%~30%、引发剂0.5%~2.0%、促进剂0.5%~2.0%、氢氧化铝40%~50%、碳酸钙粉20%~30%。采用该方法制备的人造大理石外形平整美观,压缩强度为79 MPa,弯曲强度为7.4 MPa,放射性比活度IRaIr分别为0.67、0.45,质量符合国家标准。

关 键 词:油页岩  灰渣  不饱和聚酯树脂  大理石  促进剂  
收稿时间:2010-08-26

Preparation and Property Analysis of Artificial Marble from Oil Shale Ash
GAN Shu-cai,YANG Chun-ming,XU Ji-jing,LAI Ya-wen,LI Guang-huan,XIAO Guo-shi.Preparation and Property Analysis of Artificial Marble from Oil Shale Ash[J].Journal of Jilin Unviersity:Earth Science Edition,2011,41(3):879-884.
Authors:GAN Shu-cai  YANG Chun-ming  XU Ji-jing  LAI Ya-wen  LI Guang-huan  XIAO Guo-shi
Institution:1.College of Chemistry, Jilin University, Changchun130026, China;
2.College of GeoExploration Science and Technology, Jilin University, Changchun130026, China;
3.Experimental Center of Testing Science, Jilin University, Changchun130026, China
Abstract:A novel kind of artificial marble has been synthesized by room temperature curing method,using oil shale ash and unsaturated polyester resin as the main raw materials,assisted by curing agent and accelerating agent.The effects of physicochemical properties on the performance of as-prepared samples have been investigated systematically,including the proportion of raw materials,the content of curing agent and accelerating agent,curing time,the type of resin and packing size.According to experiment,the optimiz...
Keywords:oil shale  ash  unsaturated polyester resin  marble  accelerating agent  
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