Experiments and geochemical modelling of CO2 sequestration by olivine: Potential,quantification

Aqueous solutions equilibrated with supercritical CO₂ (150 °C and total pressure of 150 bar) were investigated in order to characterize their respective conditions of carbonation. Dissolution of olivine and subsequent precipitation of magnesite with a net consumption of CO₂ were expected. A quantified pure mineral phase (powders with different olivine grain diameter [20–80 μm], [80–125 μm], [125–200 μm] and [>200 μm]), and CO₂ (as dried ice) were placed in closed-batch reactors (soft Au tubes) in the presence of solutions. Different salinities (from 0 to 3400 mM) and different ratios of solution/solid (mineral phase) (from 0.1 to 10) were investigated. Experiments were performed over periods from 2 to 8 weeks. Final solid products were quantified by the Rock-Eval 6 technique, and identified using X-ray diffraction, Raman spectroscopy, electron microprobe and scanning electron microscopy. Gaseous compounds were quantified by a vacuum line equipped with a Toepler pump and identified and measured by gas chromatography (GC). Carbon mass balances were calculated.