Confined pyrolysis of Tertiary lacustrine source rocks in the Western Qaidam Basin,Northwest China: Implications for generative potential and oil maturity evaluation

The parameter S₁ + S₂ (genetic potential) of Rock-Eval analysis is widely used as an evaluation of the genetic potential for the source rocks. Oligocene–Miocene saline lacustrine source rocks in the western Qaidam basin have low total organic C contents (TOC), most around 0.5% with a few exceptions >1.0%. Mineral matrix effects are substantial for source rocks with low TOC, resulting in relatively low S₁ and S₂ peaks. Based on the results of confined pyrolyses (sealed Au capsules) on 6 Oligocene–Miocene source rocks from the western Qaidam basin, with TOC ranging between 0.48% and 2.22%, the relationship between the S₁ + S₂ parameter and the maximum amount of extracted bitumen or saturated and aromatic hydrocarbons (SA) after the confined pyrolysis has been established as follows: bitumen (mg/g rock) = 1.4924 × (S₁ + S₂) + 0.3201 (r = 0.987), or SA (saturates + aromatics) (mg/g rock) = 0.7083 × (S₁ + S₂) + 0.4045 (r = 0.992). Based on these formulas, the amounts of hydrocarbons generated from source rocks can be reasonably estimated. The typical crude oils with low biomarker maturities in this region appear substantially different to the pyrolysates of these six rocks at 180–300 °C but comparable to the pyrolysates at 320 °C and higher temperatures based on molecular parameters. This result, in combination with the physical and gross compositions of the crude oils, suggests that the majority of these crude oils were generated from the source rocks during the main oil-generative stage, possibly at a maturity higher than R_o 0.74%.