F-phlogopites in the Alban Hills Volcanic District (Central Italy): indications regarding the role of volatiles in magmatic crystallisation

A systematic analysis of micas contained in effusive, pyroclastic and hypabyssal rocks of the Alban Hills Volcanic District (AHVD) (Central Italy) was made in order to characterise minerals of pyroclastic units for tephrostratigraphy and to obtain as much information as possible on the activity of volatiles in this magmatic system. The phlogopite shows a large range of F contents (between 0.50 and 7.50 wt%) that make it possible to discriminate different AHVD lithologies; in particular, micas of lava groundmass are characterised by extremely high F (up to 7.50 wt%) and Ba (up to 9.70 wt%) contents, seldom or never found in other magmatic ultrapotassic rocks. Moreover, the micas of pyroclastics, ultramafic cumulates and holocrystalline inclusions made up of leucite, clinopyroxene and phlogopite (hereafter italites) show Mg/(Mg+Fe) values between 0.65 and 0.90 that are not correlated with F contents. The variations in F contents observed in the AHVD micas do not appear to be due to a “temperature” effect or pressure changes, but they may be due to variations in the H₂O and CO₂ activities in the magma chamber. They make it possible to differentiate three crystallisation environments in the AHVD magmatic system. The first one had elevated CO₂ activity and formed the italites near the carbonate contact; these rocks represent, at least those enriched in clinopyroxene without skarn-minerals, the hypabyssal crystallisation of the AHVD magmas at the periphery of magma chamber. The second one, characterised by a higher water activity, is represented by the micas of the ultramafic cumulates and pyroclastic scorias, and is located in the inner part of magma chamber. The third environment, the groundmass of the lavas, it is not related with the previous ones and is characterised by the absence of water and by a high F activity. In general, our results suggest that the compositional variations observed in the micas (Al, Si, Ti, Ba) reflect different H₂O activities (inversely correlated with F activity) in the magma chamber.