Comparison of automatic classification methods applied to lake geochemical samples

Geochemical samples from part of Lake Geneva were analyzed for 29oxides and trace elements. The variables and samples were subjected to R- and Q-mode analyses. The following techniques were applied in sequence: data transformation (normalization and standardization), data reduction (principal component and factor analysis), and automatic classification (dendrograph). The data were treated using various combinations of these techniques, and the resulting classifications evaluated by means of several criteria. The best classification of the samples is given by a cluster analysis performed on four principal components computed from standardized variables. The discriminatory power of the variables also was measured and determined to depend on their degree of intercorrelation. As a final result, the 29original variables were reduced to four components and the sediment samples classified into four facies, leading to easily interpretable geochemical maps.