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察尔汗盐湖正构烷烃和单体碳同位素分布特征及其古植被意义
引用本文:郭金春,刘清浩,马海州,胡建芳.察尔汗盐湖正构烷烃和单体碳同位素分布特征及其古植被意义[J].地球化学,2010,39(6):566-573.
作者姓名:郭金春  刘清浩  马海州  胡建芳
作者单位:[1]中国科学院 广州地球化学研究所 有机地球化学国家重点实验室, 广东广州510640 [2]中北大学化工与环境学院, 山西太原030051 [3]中国科学院 青海盐湖研究所, 青海西宁810008
基金项目:中国科学院有机地球化学国家重点实验室开放基金资助项目
摘    要:对察尔汗盐湖ISL1A钻孔沉积物样品进行了有机分子地球化学分析, 检测出了丰富的类脂物, 包括正构烷烃、一元正脂肪酸、一元正脂肪醇等, 本文主要讨论正构烷烃类脂物的分布特征。正构烷烃的分布型式表明其来源于低等菌藻类生物和陆生高等植物, 正构烷烃的高碳数部分均有显著的奇偶优势, 高碳数正构烷烃全部以C31 为主峰碳。正构烷烃分布特征表明在110.1~50.1 ka B.P.期间, 察尔汗盐湖地区为草原植被景观。对C27、C29、C31 长链正构烷烃进行了单体碳同位素测定, 利用二元模式估算了C3 和 C4 植物的相对输入贡献, 结果表明, 以C3 植物为主。

关 键 词:湖泊沉积物  正构烷烃  碳同位素  古植被  察尔汗盐湖

Chemical and compound-specific carbon isotopic characteristics of n-alkanes in the Qarhan Salt Lake sediments and their paleovegetation significance
GUO Jin-chun,LIU Qing-hao,MA Hai-zhou,HU Jian-fang.Chemical and compound-specific carbon isotopic characteristics of n-alkanes in the Qarhan Salt Lake sediments and their paleovegetation significance[J].Geochimica,2010,39(6):566-573.
Authors:GUO Jin-chun  LIU Qing-hao  MA Hai-zhou  HU Jian-fang
Institution:1. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;2. School of Chemical Engineering and Environment, North University of China, Taiyuan 030051, China;3. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China)
Abstract:Molecular biomarkers, including n-alkanes, n-alcohols and n-alkanoic acids, were identified in the core sediments taken from the Qarhan Salt Lake by GC/MS analysis. The distribution of n-alkanes was mainly discussed in this paper. The n-alkanes exhibited strong odd-over-even carbon number predominance and the main peak at C31, suggesting that they were derived from terrestrial higher plants. The distribution of n-alkanes indicated that the grass vegetation was dominated in the Qarhan Salt Lake area during 110.1 ka B.P. to 50.1 ka B.P. In addition, the compound-specific carbon isotopic composition was determined for C27, C29 and C31 n-alkanes in the core. Relative contribution of C3 and C4 plants was estimated by using a binary model, indicating that C3 plants are a dominantinput.
Keywords:lake sediments  n-alkanes  carbon isotope  paleo-vegetation  Qarhan Salt Lake
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