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Methane in the East China Sea water
Authors:Nobuo Tsurushima  Shuichi Watanabe  Shizuo Tsunogai
Institution:(1) Department of Chemistry, Graduate School of Fisheries Sciences, Hokkaido University, 041 Hakodate, Japan;(2) Laboratory of Marine and Atmospheric Geochemistry Graduate School of Environmental Earth Science, Hokkaido University, 060 Sapporo, Japan
Abstract:Methane in the East China Sea water was determined four times at a fixed vertical section along ldquoPN linerdquo consisting of 11–14 stations, in February 1993, October 1993, June 1994 and August 1994. The mean concentration of methane in the surface water was not significantly higher than that in the open ocean. The methane concentration below the pycnocline increased during the stratified period in summer to autumn and reached to 15 nmoles/l at most in October. The concentration of methane was fairly well correlated with AOU in the layer below the pycnocline in the stratified season. This means that methane in the bottom water has only a single source, which is expected to be anoxic sediments near the coast, and that the oxidation rate of methane in the water is extremely slow in the oxic water. The high methane observed in October completely disappeared in February, indicating that the methane was escaped to the atmosphere or transported to the pelagic ocean by the Kuroshio current. The East China Sea, therefore, is not a large direct and stationary source for the atmospheric methane, but may have some role as a source by supplying it sporadically to the atmosphere in early winter or indirectly from the surface of the pelagic ocean.
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