| 正十六烷与硫酸镁热氧化还原反应模拟实验研究 |
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| 引用本文： | 岳长涛,李术元,徐明,张永翰,钟宁宁.正十六烷与硫酸镁热氧化还原反应模拟实验研究[J].地球化学,2011,40(2):171-178. |
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| 作者姓名： | 岳长涛 李术元 徐明 张永翰 钟宁宁 |
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| 作者单位： | 中国石油大学重质油国家重点实验室;大庆油田有限责任公司新能源办公室;中国石油大学资源与信息学院; |
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| 基金项目： | 国家自然科学基金(40702019) |
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| 摘 要： | 利用高压釜反应装置,在一定温度和压力下,对正十六烷与硫酸镁热化学还原反应含水体系进行了模拟,通过气相色谱仪、微库仑仪、毛细管气相色谱,脉冲火焰光度检测器、红外光谱仪及X射线衍射仪对气、油、固三相产物分别进行了分析,并进行了动力学研究.结果表明,该体系在温度为450～550℃时可以发生反应,主要生成氧化镁、硫、焦炭、硫化...
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| 关 键 词： | 有机硫化物 正十六烷 硫酸镁 模拟实验 动力学 |
Simulation experiments on the thermochemical sulfate reduction system of n-hexadecane and magnesium sulfate |
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| YUE Chang-tao,LI Shu-yuan,XU Ming,ZHANG Yong-han,ZHONG Ning-ning.Simulation experiments on the thermochemical sulfate reduction system of n-hexadecane and magnesium sulfate[J].Geochimica,2011,40(2):171-178. |
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| Authors: | YUE Chang-tao LI Shu-yuan XU Ming ZHANG Yong-han ZHONG Ning-ning |
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| Institution: | YUE Chang-tao1,LI Shu-yuan1,XU Ming2,ZHANG Yong-han1 and ZHONG Ning-ning3 1.State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Beijing 102249,China,2.New Energy Office in Daqing Oilfield Co.,Ltd.,Daqing 163453,3.Faculty of Natural Resource and Information Technology |
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| Abstract: | Thermal simulation experiments on the thermochemical sulfate reduction(TSR) system of n-hexadecane and magnesium sulfate were carried out using an autoclave operated at specified temperature and pressure in the presence of water.Properties of the gas-oil-solid 3-phase products were analyzed by some advanced analytical methods including gas chromatography,microcoulometry,capillary gas chromatography combined with a pulsed flame photometric detector(GC-PFPD),FT-IR and X-ray diffraction.The results show that t... |
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| Keywords: | organic sulfur compounds n-hexadecane magnesium sulfate simulation experiment kinetic |
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