Geochemical evolution of Archaean granulite-facies gneisses in the Vestfold Block and comparisons with other Archaean gneiss complexes in the East Antarctic Shield

The Vestfold Block, like other Archaean cratons in East Antarctica and elsewhere, consists predominantly of felsic orthogneiss (Mossel and Crooked Lake gneisses), with subordinate mafic granulite (Tryne metavolcanics) and paragneiss (Chelnok supracrustals). Two major periods of continental crust formation are represented. The Mossel gneiss (metamorphosed about 3,000 Ma ago) is mainly of tonalitic composition, and is similar to much of the roughly coeval Napier Complex in Enderby Land. The Crooked Lake gneiss was emplaced under high-grade conditions about 2,450 Ma ago and comprises a high proportion of more potassic rocks (monzodioritic and monzonitic suites), as well as tonalite and minor gabbro and diorite. Both Mossel and Crooked Lake gneisses are depleted in Y and have moderate to high Sr, Ce/Y, and Ti/Y, consistent with melting of a mafic source (?subducted hydrated oceanic crust) leaving major residual hornblende (± garnet). Most Crooked Lake gneisses are more enriched in incompatible elements (P, Sr, La, Ce, and particularly Rb, Ba, and K) than Mossel gneisses, suggesting derivation from a more enriched mafic source. The Vestfold Block contains few orthogneisses derived by melting of older felsic crustal rocks, in marked contrast to the Archaean Napier Complex and, in particular, southern Prince Charles Mountains. Both Mossel and Crooked Lake tonalites are strongly depleted in Rb, K, Th, and U, and have very low Rb/Sr and high K/Rb; more potassic orthogneisses are depleted in Th, U, and, to lesser extents, Rb. Tryne metavolcanics are depleted in Th and Rb, but appear to have been enriched in K (and probably Na), possibly during early low-grade alteration.