Sea-floor sediment distribution in the Gulf of Mexico

Carbonate content, smear-slide analysis and diffuse reflectance spectrophotometry were utilized to determine modern sediment composition and distribution throughout the Gulf of Mexico. In all, 186 core top and grab samples distributed throughout the Gulf were analyzed. Reflectance spectra were taken from thick smear slides from the near ultraviolet, through the visible, and into the near infrared. The first derivatives of the percent reflectance data were subjected to factor analysis producing factors that grouped covarying first-derivative wavelengths. Factors were interpreted by comparison to first-derivative curves for known sediment components and minerals. Interpretation was aided by the mapping of both calcium carbonate content and smear-slide sediment classes. The most easily interpreted factor solution was produced by analyzing only the visible region of the spectrum and extracting seven factors which explained 98% of the cumulative variance. These factors, in order of their relative importance, are interpreted as (1) marl and calcareous clay, (2) glauconite, (3) kaolinite, (4) organic matter, (5) phosphorite, (6) hematite, and (7) goethite. Some factor maps are consistent with known sources of fluvial sediment input; for example, kaolinite is deposited off rivers draining the southeastern US. Other factor maps are related to the origin of the material in the factor, glauconite, for example, being confined to low sedimentation regions of the outer shelf. The most unusual observation concerns the distribution of hematite, which appears to be transported from the rivers of south Texas, primarily the Rio Grande, across the shelf then eastward downslope along the base of the Sigsbee Escarpment. This eastward transport seems to be explainable only by transport in bottom currents flowing along the base of the Sigsbee Escarpment.