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锶在砂岩和花岗岩中的分配系数及吸附机制研究
引用本文:王青海,李晓红,顾义磊,陈金华.锶在砂岩和花岗岩中的分配系数及吸附机制研究[J].矿物岩石,2004,24(2):30-34.
作者姓名:王青海  李晓红  顾义磊  陈金华
作者单位:1. 重庆大学西南资源开发及环境灾害控制工程教育部重点实验室,重庆,400044;新疆马兰63653部,新疆,马兰,841700
2. 重庆大学西南资源开发及环境灾害控制工程教育部重点实验室,重庆,400044
3. 重庆交通学院,重庆,400074
摘    要:采用批示法(BATCH)研究不同浓度条件下^87Sr在某放射性废物预选处置场围岩—花岗岩和砂岩中的吸附比,并利用面积修正公式求取分配系数。花岗岩和砂岩对^87Sr的吸附机制研究结果表明:花岗岩和砂岩对^87Sr的吸附机制为岩石中的Ca和K与水中的Sr之间的离子交换。由于砂岩中长石含量大,且胶结物质为钙质和泥质,因此砂岩对。^87Sr的吸附能力比花岗岩强。

关 键 词:  批示法  砂岩  花岗岩  离子交换  分配系数  吸附
文章编号:1001-6872(2004)02-0030-05
修稿时间:2004年1月9日

RESEARCH ON THE DISTRIBUTION COEFFICIENT AND THE ABSORPTION MECHANISM FOR Sr IN GRANITE AND SANDSTONE
WANG Qing-hai.RESEARCH ON THE DISTRIBUTION COEFFICIENT AND THE ABSORPTION MECHANISM FOR Sr IN GRANITE AND SANDSTONE[J].Journal of Mineralogy and Petrology,2004,24(2):30-34.
Authors:WANG Qing-hai
Institution:WANG Qing-hai~
Abstract:Absorption ratio represents the distributing concentration ratio of a solute between solid phase and liquid phase.With Batch way, this paper mainly studies ()~(87)Sr absorption ratio in granite and sandstone which are the bedrocks in some radioactive waste disposal field in China and the absorption ratio change with ()~(87)Sr concentrations in water.The distribution coefficient with area revision formula for ()~(87)Sr in granite and sandstone and their absorption mechanism are calculated and analyzed.The result indicates that the absorption mechanism of granite and sandstone absorbing ()~(87)Sr is the ionic exchanges between ()~(87)Sr in water and Ca and K in granite and sandstone.As there is more feldspar in sandstone than in granite ,and the cement in sandstone is calcareous and mud, so the ability of ()~(87)Sr absorption of sandstone is stronger than that of granite.
Keywords:distribution coefficient  absorption  ionic exchange
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