Distribution surfaces in solvent extraction systems

In the solvent extraction of metals, the distribution of the metal is usually dependent on the concentrations of several different species in the two phases. Despite this fact, distribution isotherms are usually presented as plots of C_o as a function of C_aq and these are used for a McCabe-Thiele type evaluation of a number of stages and flow rates, etc., each individual isotherm being valid only for one set of initial conditions; this treatment limits the possibilities of optimizing the system. In the present paper an extension of three-dimensional plots is suggested with special reference to the Cu/LIX64N extraction system. The distribution surface is defined and the general properties of the plots are outlined.A procedure is outlined whereby the surface can be represented on a two dimensional plot and a theoretical model for the surface can be superimposed.The paper also shows how distribution ratios (D values) are related to the surface.