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Determining the extent of weathering of spilled fuel in contaminated soil using the diastereomers of pristane and phytane
Authors:Cameron P. McIntyre   Paul McA. Harvey   Susan Ferguson   Anna M. Wressnig   Ian Snape  Simon C. George
Affiliation:aCSIRO Petroleum, P.O. Box 136, North Ryde, NSW 1670, Australia;bAustralian Antarctic Division, Channel Hwy, Kingston, TAS 7050, Australia;cHochsteingasse 70, Graz A-8010, Austria;dDepartment of Earth and Planetary Sciences, Macquarie University, North Ryde, NSW 2109, Australia
Abstract:A method is described for determining the relative extent of weathering in moderately biodegraded, hydrocarbon-contaminated soils from Antarctica. Plotting the pristane diastereomer ratio (PrDR) vs. pristane/phytane (Pr/Ph) allows the relative extent of weathering (primarily evaporation in this case) to be determined. PrDR is used to account for biodegradation as it is independent of evaporation. The method is straightforward and as robust as conventional ratios.
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