Melilitite-carbonatite tuffs in the Laetolil Beds of Tanzania

The upper unit of the Laetolil Beds, 45 to 60 m thick, is about 80% wind worked or eolian tuff and 20% air-fall tuff. The air-fall tuffs comprise a phonolitic tuff and numerous thin tuffs of original melilitite-carbonatite composition. Most of the melilitite-carbonatite tuffs consist largely of sand-sized lava globules and crystals cemented by calcite. Evidence of former carbonatite ash is provided by calcite globules, fenestral textures, and high contents of Ba and Sr in early-deposited calcite. These air-fall tuffs were produced by volatile-rich eruptions of highly fluid magma. In a typical eruptive cycle, lava droplets were followed by crystals which increased in size during the eruption. Commonly the final event was an eruption of fine ash and carbonatite globules. Particularly violent explosions ejected blocks of lava and plutonic rock 10 to 15 cm in diameter for distances of 20 km.The climate was semiarid, and melilitite-carbonatite ash layers were first cemented by soluble salts such as trona resulting from incongruent solution of the carbonatite ash by rainfall. Repeated solution and crystallization of salts resulted in a polygonal fracture pattern in the thinner tuffs. Ash layers not cemented by soluble salts were eroded and redeposited by wind to form eolian tuffs. Subsequently both the air-fall and eolian tuffs were modified by several diagenetic stages, mostly in the vadose zone, to form rocks consisting principally of montmorillonite, phillipsite, and calcite. At an early stage calcium carbonate derived from carbonatite ash was precipitated as micrite both as a cement and replacement of organic matter. Glass, nepheline, and melilite were now weathered to clay, releasing components to form phillipsite. Calcite spar was precipitated last, as a replacement, cement, and pore filling. Unaltered glass, preserved in some of the eolian tuffs, has an unusually high content of Na, K, and Fe for a melilitite composition.These beds contain a rich fauna, notable for the excellent preservation of delicate fossils such as bovid dung, land snails, and bird eggs. This preservation is attributed, at least in part, to carbonatite ash. Carbonatite ash was also responsible for the preservation of footprints in one of the tuffs.