222Rn and 226Ra: indicators of sea-ice effects on air-sea gas exchange

²²² Rn and ²²⁶Ra distributions beneath the sea ice of the Barents Sea revealed that ice cover has varied effects on air-sea gas exchange. Twice, once in late summer and once in late winter, seawater samples from the top meter below drill holes had ²²²Rn activities that were not lower than their ^226,Ra activities, indicating the existence of secular equilibrium and a negligible net exchange of ²²²Rn and other gases with the atmosphere. However, seawater in the upper 20-85 m usually exhibited at least some ²²²Rn depletion; ²²²Rn-to-²²⁶Ra activity ratios tended to have 'ice-free' values (0.3-0.9) in the summer and values between 0.9 and 1.0 in the winter. Integrated ²²²Rn depletions and piston velocities in both seasons typically fell in the lower 25% of the ranges for ice-free seawater, suggesting that a moderate but far from total reduction in gas exchange is normally caused by ice cover and/or meltwater. The results demonstrate that sea-ice interference with the oceanic uptake of atmospheric gases such as CO, is not well understood and needs further investigation.