| 氢化物发生-原子荧光光谱法测定植物样品中汞硒砷 |
| |
| 引用本文： | 赵 斌,陈志兵,董 丽.氢化物发生-原子荧光光谱法测定植物样品中汞硒砷[J].岩矿测试,2010,29(3):319-321. |
| |
| 作者姓名： | 赵 斌 陈志兵 董 丽 |
| |
| 作者单位： | 江苏省地质调查研究院,江苏,南京,210018 |
| |
| 摘 要： | 植物样品经硝酸-高氯酸一次湿法消解后,用氢化物发生-原子荧光光谱法同时测定汞、硒、砷。测定时加入消泡剂磷酸三丁酯,可有效消除泡沫,降低记忆效应,提高精密度。方法精密度(RSD,n=12)为汞2.96%,硒0.96%,砷2.49%。经加标回收试验和国家一级标准物质验证,测定结果与标准值吻合。
|
| 关 键 词： | 氢化物发生 原子荧光光谱法 汞 硒 砷 植物样品 |
| 收稿时间： | 2009/8/19 0:00:00 |
| 修稿时间： | 2010/1/12 0:00:00 |
Determination of Hg, Se and As in Plant Samples by Hydride Generation-Atomic Fluorescence Spectrometry |
| |
| ZHAO Bin,CHEN Zhi-bing and DONG Li.Determination of Hg, Se and As in Plant Samples by Hydride Generation-Atomic Fluorescence Spectrometry[J].Rock and Mineral Analysis,2010,29(3):319-321. |
| |
| Authors: | ZHAO Bin CHEN Zhi-bing and DONG Li |
| |
| Institution: | Geological Survey of Jiangsu Province, Nanjing 210018, China;Geological Survey of Jiangsu Province, Nanjing 210018, China;Geological Survey of Jiangsu Province, Nanjing 210018, China |
| |
| Abstract: | A method for simultaneous determination of mercury, selenium and arsenic in plant samples by atomic fluorescence spectrometry was developed. The samples were digested with HNO3-HClO4 and tributyl phosphate (TBP) was added for effectively eliminating foam, reducing memory effect and improving the accuracy. The method has been applied to the determination of trace Hg, Se and As in National Standard Reference Materials and the results are in agreement with certified values. The recovery test was satisfactory with precision (RSD, n=12) of 2.96%, 0.96% and 2.49% for Hg, Se and As, respectively. |
| |
| Keywords: | hydride generation atomic fluorescence spectrometry mercury selenium arsenic plant sample |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《岩矿测试》浏览原始摘要信息 |
| 点击此处可从《岩矿测试》下载免费的PDF全文 |
|
