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九连墩楚墓青铜器锈蚀产物的拉曼光谱分析
引用本文:罗武干,秦颖,王昌燧,胡雅丽.九连墩楚墓青铜器锈蚀产物的拉曼光谱分析[J].岩矿测试,2007,26(2):138-140.
作者姓名:罗武干  秦颖  王昌燧  胡雅丽
作者单位:1. 中国科学技术大学科技史与科技考古系,安徽,合肥,230026
2. 中国科学院研究生院科技史与科技考古系,北京,100049
3. 湖北省文物考古研究所,湖北,武汉,430077
基金项目:国家自然科学基金;中国科学院知识创新工程项目
摘    要:利用拉曼光谱对几件九连墩楚墓出土青铜器的腐蚀产物进行了测试。结果表明,九连墩楚墓出土的青铜器上主要的锈蚀产物为孔雀石CuCO_3·Cu(OH)_2],存在部分蓝铜矿2CuCO_3·Cu(OH)_2]和少许副氯铜矿Cu_2(OH)_3Cl];此批青铜器锈蚀情况比较复杂,锈蚀种类比较丰富。在此基础上,探讨了科学保护此批青铜器的方法。

关 键 词:拉曼光谱法  腐蚀产物  青铜器  九连墩楚墓
文章编号:0254-5357(2007)02-0138-03
收稿时间:2006/6/27 0:00:00
修稿时间:2006-06-272006-09-25

Raman Spectrometric Analysis of Corrosion Products from Ancient Bronzes Excavated from Jiuliandun Tombs
LUO Wu-gan,QIN Ying,WANG Chang-sui,HU Ya-li.Raman Spectrometric Analysis of Corrosion Products from Ancient Bronzes Excavated from Jiuliandun Tombs[J].Rock and Mineral Analysis,2007,26(2):138-140.
Authors:LUO Wu-gan  QIN Ying  WANG Chang-sui  HU Ya-li
Institution:1. Department of Scientific History and Archaeometry, University of Science and Technology of China, Hefei 230026, China; 2. Department of Scientific History and Archaeometry, Graduate University of the Chinese Academy of Sciences, Beijing 100049, China; 3. Institution of Cultural Relics and Archaeology of Hubei Province, Wuhan 430077, China
Abstract:Raman microspectrometry was used to identify the corrosion products from ancient bronzes excavated from Jiuliandun tombs. The results indicate that malachite \CuCO3·Cu(OH)2\] is the main substance of green corrosion product; azurite \2CuCO3·Cu(OH)2\] is the main substance of blue corrosion product and paratacamite \Cu2(OH)3Cl\] is the main substance of slightly green corrosion product. Based on the analytical results, the scientific methods for protection of the ancient bronzes are proposed.
Keywords:Raman spectrometry  corrosion product  bronze  Jiuliandun tomb
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