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松节油加氢热解产物中单萜烷类化合物的初步研究
引用本文:王培荣,徐冠军,赵红,王峰.松节油加氢热解产物中单萜烷类化合物的初步研究[J].地球化学,2007,36(6):535-538.
作者姓名:王培荣  徐冠军  赵红  王峰
作者单位:1. 中国石油天然气股份有限公司,油气地球化学重点实验室,北京,100083;长江大学,有机地球化学系,湖北,荆州,434023
2. 中国石油天然气股份有限公司,油气地球化学重点实验室,北京,100083;中国石油勘探开发研究院,石油地质实验研究中心,北京,100083
3. 长江大学,有机地球化学系,湖北,荆州,434023
4. 中国石油天然气股份有限公司,北京,100011
摘    要:用雷尼镍为催化剂对松节油进行了加氢实验,获得顺蒎烷、反蒎烷、莰烷、异莰烷等单萜烷类化合物,采用气相色谱"反吹、微流控"技术的色谱-质谱分析方法,测得了它们的保留时间和质谱图,为进一步研究原油或抽提物轻馏分中单萜烷类化合物的地球化学意义提供了一些基础性数据.

关 键 词:单萜烷  原油轻馏分  色谱-质谱  有机地球化学
文章编号:0379-1726(2007)06-0535-04
修稿时间:2007-05-25

Identification of monoterpanes in hydrogenated turpentine
WANG Pei-rong,XU Guan-jun,ZHAO Hong,WANG Feng.Identification of monoterpanes in hydrogenated turpentine[J].Geochimica,2007,36(6):535-538.
Authors:WANG Pei-rong  XU Guan-jun  ZHAO Hong  WANG Feng
Institution:1. Key LaboratoryofPetroleum Geochemistry, PetroChina Company Limited, Beijing 100083, China; 2. Central Laboratory of Petroleum Geology, Research Institute of Petroleum Exploration and Development, PetroChina, Belling 100083, China;3. Department of Organic Geochemistry, Yangtze University, Jingzhou 434023, China; 4. PetroGhina Company Limited, Belling 100011, China
Abstract:Raney nickel catalyst was used in hydrogenation of the turpentine and c-pinane,t-pinane,camphene and isocamphane and some other monoterpanes were determined.The retention time and mass spectrum chromatogram of the monoterpanes were obtained by both FID and MSD analyzer equipped with backflush and micro-flow controller.This study provides some basic data for further research on the geochemistry significance of monoterpanes in the light fraction of crude oil and extraction of source rock.
Keywords:monoterpane  light fraction of oil  GC/MS  organic geochemistry
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