| Abstract: | The Permo-Carboniferous Schmidgaden, Weiden, Erbendorf and Stockheim basins from southern Germany host discontinuous seams of high ash coal and carbargillites which were mined for hard coal, explored for uranium and only recently have proved their source rock potential for gaseous and fluid hydrocarbons. Alteration and facies of these carbonaceous beds were geologically and chemically investigated. During silicification which is exclusively confined to the carbonaceous interbeds of pyroclastic depositions, element depletion prograded except for Zn, Pb, U. The anoxic environments under consideration may be subdivided into fluvial/swamp (Upper Westphalian beds from Schmidgaden, Weiden, Erbendorf and Stockheim) and lacustrine depositions (Upper Stephanian and Upper Autunian carbargillites from Erbendorf, Weiden-Bechtsrieth). SiO2, MgO, CaO, Mo and Zr have proved to be most suitable for recognition of these environments, whereas, U, K2O and notably Cu/Zn are less appropriate. In the ternary plots displaying the organic chemistry of extracts of these carbonaceous beds fluvial swamps have low and lacustrine beds high contents of saturated hydrocarbons. All samples show a pronounced OEP (=odd even predominance) of n-alkanes which partly are environment-controlled (terrestrial origin), partly maturity-controlled. The high iso- and cyclo-alkanes of Schmidgaden and bimodal n-alkyl distribution point to a contribution of algal material. Finally four basin types bearing carbonaceous rocks are discussed with respect to their economic potential and compared with basins elsewhere (Cerilly, Lodève, St. Hippolyte, Uinta): type I: intramontane fault-bounded basin (swamp), type II: volcanic-depression with steep relief (swamps), type III: halfgraben (lake), type IV: volcanic-depression with smooth relief (lake). Types I and II are of interest for hard coal, organic-hosted U-deposits and mainly gasprone; types III and IV, however, show good source-rock potential for crude oil. |
