Tracking Holocene environmental changes in an alpine lake sediment core: application of regional diatom calibration, geochemistry, and pollen

Diatom abundances in the surface sediment samples of 41 mountain lakes in the central Austrian Alps (Niedere Tauern) were related to environmental variables using multi-variate techniques. Canonical correspondence analysis (CCA) revealed that the pH, date of autumn mixing (A _mix), mean August water temperature (T _Aug), dissolved organic carbon (DOC), and relative water depth (Z _rel) made significant contributions to explain the diatom assemblage variation in the lakes of the training set. A weighted averaging partial least square regression and calibration model was used to establish Di-pH (R ² _boot= 0.72, RMSEP_boot= 0.131), and a thermistor measurements-based PLS model for A _mix (R ² _boot= 0.71, RMSEP_boot= 0.006 log₁₀ Julian days). The latter showed a better prediction than T _Aug, and was used in terms of climate change. These transfer functions, together with analyses of loss on ignition (LOI), the total carbon/nitrogen (C/N)-ratios, and selected pollen, were applied to an early to mid-Holocene (11.5–4 cal. ky BP) sediment core section from an Austrian Alpine treeline lake on crystalline bedrock. Additionally, passive sample scores in the CCA of the diatom training set were used to show trends in the variables DOC and Z _rel. During the early Holocene, diatoms indicative of increased pH, extended warm summers, and low water levels dominated. Between 10.2 and 7.6 cal. ky BP it was followed by diatom assemblages that indicated an increase in lake water depth and an earlier A _mix. The multi-proxy data suggest that the A _mix decline is the result of a series of snow-rich summer cool and wet climate fluctuations, which were divided by climate warming at ∼9 cal. ky BP. Increased A _mix, LOI and DOC, and the correspondent decline in the C/N-ratios, show subsequent climate warming between 7.3 and 6 cal. ky BP. The long-term trend in Di-pH indicates the impact of catchment-related processes during the early-Holocene, that were superimposed by climate.