Contrasting mineral parageneses in high-temperature calc-silicate granulites: examples from the Eastern Ghats, India |
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Authors: | S DASGUPTA |
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Institution: | Department of Geological Sciences, Jadavpur University, Calcutta-700 032, India |
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Abstract: | Abstract Three types of mineral associations are described from calc-silicate granulites from the Eastern Ghats, India, where geothermobarometry in associated rocks suggests extremely high P–T conditions of metamorphism ( c . 9 ± 1 kbar, 950° C). These mineral associations are: (i) calcite + quartz + scapolite + plagioclase, (ii) calcite + scapolite + wollastonite + porphyroblastic garnet + coronal garnet and (iii) calcite + quartz + wollastonite + scapolite + porphyroblastic garnet + coronal garnet, all coexisting with K-feldspar, titanite and clinopyroxene. The first two associations evolved through nearly isobaric cooling retrograde paths, whereas the third evolved through a nearly isothermal decompression path followed by an isobaric cooling retrograde path. Textural and compositional characteristics suggest the following mineral reactions in the calc-silicate granulites: calcite + quartz = wollastonite + CO2, calcite + plagioclase = scapolite, calcite + scapolite + wollastonite = porphyroblastic garnet ± quartz + CO2, CaTs + wollastonite = coronal garnet (association ii) and wollastonite + scapolite = coronal garnet (association iii) + quartz + CO2. Andradite content in garnet was buffered by the redox equilibria wollastonite + hedenbergite + O2= andradite + quartz (association iii) and wollastonite + andradite + CaTs + scapolite = hedenbergite + calcite + grossular + O2 (association ii). The contrasting mineral parageneses have been ascribed to interplay of variables such as X CO2, f O2, f HCl in the fluid, bulk Na content and the nature of the retrograde P–T–X CO2 paths through which the rocks evolved. |
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Keywords: | calc-silicate rocks Eastern Ghats fluid composition high-temperature metamorphism retrograde path |
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