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VARIATIONS IN ISOTOPIC COMPOSITIONS OF CHLORINE IN EVAPORATION-CONTROLLED SALT LAKE BRINES OF QAIDAM BASIN,CHINA
引用本文:肖应凯,刘卫国,周引民,王蕴慧.VARIATIONS IN ISOTOPIC COMPOSITIONS OF CHLORINE IN EVAPORATION-CONTROLLED SALT LAKE BRINES OF QAIDAM BASIN,CHINA[J].中国海洋与湖沼学报,2000,18(2):169-177.
作者姓名:肖应凯  刘卫国  周引民  王蕴慧
作者单位:XIAO Ying kai,LIU Wei guo ZHOU Yin min,WANG Yun hui )(Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining 810008,China) Shirodkar,P. V. (National Institute of Oceanography,Dona Paula,Goa,403 004,India)
基金项目:Project4 91 73 1 63supportedbyNSFC
摘    要:INTRODUCTIONChlorinehastwonaturallyoccuringstableisotopes, 35Cland 37Cl.Severalstudiesreportedthevariationsintheisotopiccompositionofchlorineinnature.However,intheearlyyearsOwenandSchaeffer(1955)reportednoobservabledifferenceinthe 37Cl35Clratiosintensamplesex…

收稿时间:3 June 1998
修稿时间:10 March 1999

Variations in isotopic compositions of chlorine in evaporation-controlled salt lake brines of Qaidam Basin, China
Xiao Ying-kai,Liu Wei-guo,Zhou Yin-min,Wang Yun-hui,P. V. Shirodkar.Variations in isotopic compositions of chlorine in evaporation-controlled salt lake brines of Qaidam Basin, China[J].Chinese Journal of Oceanology and Limnology,2000,18(2):169-177.
Authors:Xiao Ying-kai  Liu Wei-guo  Zhou Yin-min  Wang Yun-hui  P V Shirodkar
Institution:(1) Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining, China;(2) National Institute of Oceanography, 403 004 Dona Paula, Goa, India
Abstract:The variations in the isotopic compositions of chlorine in evaporation-controlled saline lake brines were determined by using an improved procedure for precise measurement of chlorine isotopes based on Cs2Cl+ ion by thermal ionization mass spectrometry. The results showed that variation in δ37 Cl values in these evaporation-controlled brines are attributable to evaporation of brine accompanied by the deposition of saline minerals. The isotopic fractionation of chlorine between the deposited saline mineral and the co-existing brine caused the variation of δ37 Cl values in the brine. In general the isotopic fractionation of chlorine in nature indicates enrichment of37Cl in the solid phase relative to35Cl. The reverse isotopic fractionation of chlorine in which35Cl is enriched in the solid phase, was observed to some extent during quick deposition under laboratory conditions as well as in nature. The mechanism of isotopic fractionation of chlorine during evaporation deposition was studied. Project 49173163 supported by NSFC.
Keywords:chlorine  isotopic composition  salt lakes
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