Hydrogeochemical background based on spring waters (Lubuskie Lakeland,western Poland)

Hydrogeochemical background determined for an investigated environment, defines characteristic range of its hydrochemical characteristics. This allows to observe the temporal changes of the chemical water properties taking place in the studied environments, such as due to human impact. The paper presents the results of study on the present-day hydrogeochemical background in the Lubuskie Lakeland, the region repeatedly covered by the ice sheets during the Pleistocene and little affected by anthropogenic impact. The hydrogeochemical background was established on a basis of physicochemical analyses of spring waters sampled every 3 months between November 2011 and October 2013 from 20 springs. Present-day hydrogeochemical background was assumed to be represented by values ranging between 16 and 84 percentiles. The ranges of hydrogeochemical background for the studied ions on the Lubuskie Lakeland, were in the lower range of the background considered for useful waters in Poland. The obtained results indicated that the studied spring waters were poorly diversified in terms of composition of main cations and anions, as well as electrical conductivity and total water hardness. However, large variability was observed for Fe_tot, Mn²⁺ and NO₃^?. Moreover, NO₃^? and SO₄^2? were noted in some cases to be in excess of national hydrogeochemical background values.