Magma mixing and convective compositional layering within the Vesuvius magma chamber

The pumice-fall deposits of the last two Plinian eruptions of Vesuvius-a.d. 79 Pompei and 3700 b.p. Avellino-show a marked vertical compositional variation from white phonolite at the base to grey tephritic phonolite at the top. In both Avellino and Pompei sequences a compositional gap separates white from grey pumice. Grey and white pumice have distinct Sr and Nd isotopic compositions (grey pumice: ⁸⁷Sr/³⁶Sr=0.70749-56, ¹⁴³Nd/¹⁴⁴Nd=0.512507 for Pompei; 0.70760-69, 0.512504 for Avellino; white pumice: 0.70757-78 for Pompei; 0.70729-42 for Avellino). K-feldspar separated from both grey and white pumice has, in all cases, a white ⁸⁷Sr/⁸⁶Sr ratio (0.70766-79 for Pompei, 0.70728-33 for Avellino). The observed variations are interpreted as reflecting a pre-eruptive zonation of the magma chamber. Although mineralogical evidence of interaction between magma and calcareous country rocks exists in both eruptions, crustal contamination has not significantly modified the isotopic signatures of the erupted products. Petrographic and isotopic evidence of syneruptive magma mingling occur in Pompei grey pumice as well as in Avellino white and grey pumice, but they do not fully explain all the observed geochemical and isotopic variations. These variations are related to the complex refilling history of the magmatic system and result by fractional crystallization and mixing processes acting within the magma chamber. Preliminary data from other Plinian and subplinian sruptions of the Somma-Vesuvius point out the repeticive behaviour of ⁸⁷Sr/⁸⁶Sr variation in the last 25 000 years, hence suggesting a single magma chamber and continuity of the feeding system.