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合金成分对Al-Zn-In-Mg-Ti牺牲阳极性能的影响
引用本文:翁松干,杜敏,黄志强,陈彦梦,赵聪敏.合金成分对Al-Zn-In-Mg-Ti牺牲阳极性能的影响[J].中国海洋大学学报(自然科学版),2012(9):64-68.
作者姓名:翁松干  杜敏  黄志强  陈彦梦  赵聪敏
作者单位:中国海洋大学化学化工学院海洋化学理论与工程技术教育部重点实验室;海洋石油工程股份有限公司蓝海检测中心
基金项目:国家科技重大专项项目(2008ZX05056-03-05)资助
摘    要:利用正交试验的配比方法炼制了不同Zn、In、Mg、Ti含量Al-Zn-In-Mg-Ti牺牲阳极9组,采用恒电流和极化曲线方法评价了牺牲阳极的电化学性能。结果表明:电流效率随着钛含量的增加呈上升趋势,随着铟含量的增加而呈下降趋势,随着锌、镁含量的增加先下降后升高。阳极为均匀溶解,未出现钝化现象,溶解过程表现出2种放电过程。最佳阳极配比(wt%)为:Zn 6.0,In 0.020,Mg 1.5,Ti 0.080,余量为Al。

关 键 词:合金成分  Al-Zn-In-Mg-Ti  牺牲阳极  电化学性能

Effect of Alloy Elements on Electrochemical Performance of Al-Zn-In-Mg-Ti Sacrificial Anode
WENG Song-Gan,DU Min,HUANG Zhi-Qiang,CHEN Yan-Meng,ZHAO Cong-Min.Effect of Alloy Elements on Electrochemical Performance of Al-Zn-In-Mg-Ti Sacrificial Anode[J].Periodical of Ocean University of China,2012(9):64-68.
Authors:WENG Song-Gan  DU Min  HUANG Zhi-Qiang  CHEN Yan-Meng  ZHAO Cong-Min
Institution:1 (1.The Key Laboratory of Marine Chemistry Theory and Technology,Ministry of Education,College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao 266100,China;2.Lanhai Testing Center,Offshore Oil Engineering Co,Ltd,Tianjin 300452,China)
Abstract:9 types of Al-Zn-In-Mg-Ti sacrificial anodes with different amounts of Zn,In,Mg,and Ti were designed by the orthogonal method and casted.The electrochemical performance of Al-Zn-In-Mg-Ti sacrificial anodes was tested with constant current method and polarization curves.The results showed that the current efficiency of the anodes increased with titanium content increasing,decreased with the amount of indium increasing,and increased first,then decreased with zinc,magnesium content increasing.The anodes dissolved uniformly without passivity,and there were two different discharging processes during the dissolution.The best recipe of the anode(wt%) was Zn 6.0,In 0.020,Mg 1.5,Ti 0.080,Al Balance.
Keywords:alloy element  Al-Zn-In-Mg-Ti  sacrificial anode  electrochemical performance
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