Structure,formation, and decomposition of APB's in calcic plagioclase

In calcic plagioclase (Ca, Na) (Al, Si) AlSi₂O₈] Al-Si ordering produces superstructures with periodic and non periodic antiphase boundaries (APB's). Crystals growing at high temperature close to the melting point and cooling fairly rapidly order by nucleation of ordered domains which grow, resulting in an irregular pattern of curved APB's (b plagioclase). A modulated structure with periodic APB's forms by continuous ordering at large undercooling below the critical ordering temperature (e plagioclase). During annealing APB's are eliminated by pairwise recombination of adjacent APB's to reduce strain energy along the boundaries thereby transforming nonstable e plagioclase into stable b plagioclase without change in chemical composition. This process is often accompanied by a chemical phase separation with APB's providing favorable surfaces for diffusion. Transformations are documented by transmission electron microscopy (TEM) micrographs illustrating the variation in morphology of APB patterns in igneous and metamorphic plagioclase. They are in agreement with Korekawa et al.'s (1978) model of intermediate plagioclase which relies on periodic stacking of basic units rather than wavelike modulations. The paper includes observations of a new type of satellite in Stillwater bytownite (‘h’ satellites) which are due to fine lamellar exsolution.