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GGR Biennial Review: Advances in Laser Ablation and Solution ICP-MS from 2008 to 2009 with Particular Emphasis on Sensitivity Enhancements,Mitigation of Fractionation Effects and Exploration of New Applications
Authors:Ricardo Arevalo Jr  Jeremy Bellucci  William F McDonough
Institution:1. Planetary Environments Laboratory, NASA Goddard Space Flight Center, Mail Code 699.0, Greenbelt, MD 20771, USA;2. Department of Geology, University of Maryland, 237 Regents Drive, College Park, MD 20742, USA
Abstract:Recent developments from 2008 to 2009 in ICP-MS engineering, methods and applications are reviewed here. Of particular emphasis are advances in: (a) maximising sensitivity and reducing elemental/isotopic fractionation during laser ablation processing; (b) developing new analytical techniques to measure major, minor and trace element abundances without depending on matrix-matched calibrating materials, pre-determined internal standard concentrations and/or multiple analytical methods; (c) applying in situ and solution-based ICP-MS techniques to the analysis of forensic materials for criminal and/or nuclear investigations; and (d) improving precision and limits of detection of laser ablation multi-collector ICP-MS measurements of (ultra) trace elemental and isotopic abundances.
Keywords:LA-ICP-MS  solution ICP-MS  isotopic fractionation  RMs  calibrators  nuclear materials  forensic applications
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