Fluxes of gases and particles above a deciduous forest in wintertime

Eddy-correlation measurements of the vertical fluxes of ozone, carbon dioxide, fine particles with diameter near 0.1 m, and particulate sulfur, as well as of momentum, heat and water vapor, have been taken above a tall leafless deciduous forest in wintertime. During the experimental period of one week, ozone deposition velocities varied from about 0.1 cm s^–1 at night to more than 0.4 cm s^-1 during the daytime, with the largest variations associated primarily with changes in solar irradiation. Most of the ozone removal took place in the upper canopy. Carbon dioxide fluxes were directed upward due to respiration and exhibited a strong dependence on air temperature and solar heating. The fluxes were approximately zero at air temperatures less than 5 °C and approached 0.8 mg m^–2 s^–1 when temperatures exceeded 15 °C during the daytime. Fine-particle deposition rates were large at times, with deposition velocities near 0.8 cm s^–1 when turbulence levels were high, but fluxes directed upward were found above the canopy when the surface beneath was covered with snow. Diffusional processes seemed to dominate fine-particle transfer across quasilaminar layers and subsequent deposition to the upper canopy. Deposition velocities for particulate sulfur were highly variable and averaged to a value small in magnitude as compared to similar measurements taken previously over a pine forest in summer.