Electron-probe studies of the earlier pyroxenes and olivines from the Skaergaard intrusion,East Greenland

Pyroxenes and olivines from the earlier stages of fractionation of the Skaergaard intrusion (Wager and Brown, 1968; Brown, 1957) have been studied using the electron microprobe. The subsolidus trend for both Ca-rich and Ca-poor pyroxenes has been established, from the Mg-rich portion of the quadrilateral to the Hed-Fs join, together with the orientations of the tie-lines joining coexisting pyroxenes. For the Mg-rich Ca-poor pyroxenes, Brown's (1957) solidus trend has been modified slightly. From a study of a previously undescribed drill core, reversals in the cryptic layering have been found in the Lower Zone. The reversals are attributed to existence within the convecting magma chamber of local temperature differences. The Skaergaard magma temperatures are postulated to have passed out of the orthopyroxene stability field into the pigeonite stability field at EnFs ratios of 7228, for Ca-free calculated compositions, and specimen 1849, a perpendicular-feldspar rock, is interpreted as straddling the orthopyroxene-pigeonite transition interval. The cessation of crystallisation of Ca-poor pyroxene and the increase in Wo content of the Ca-rich pyroxene trend have been reexamined, and Muir's (1954) peritectic reaction (pigeonite+liquid=augite) has been confirmed. The composition at which Ca-poor pyroxene starts reacting with the liquid is postulated as Wo₁₀ En_36.7Fs_{53 3}. It is suggested that the cessation of crystallisation of Ca-poor pyroxene is sensitive to the amount of plagioclase crystallising from the liquid.A complete series of accurate olivine compositions for the whole Skaergaard sequence is presented for the first time, including the compositions of the Middle Zone olivine reaction rims.