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PMF和PCA/APCS模型对南京北郊大气VOCs源解析对比研究
引用本文:高蒙,安俊琳,杭一纤,李用宇.PMF和PCA/APCS模型对南京北郊大气VOCs源解析对比研究[J].气象与环境学报,2014,30(1):43-50.
作者姓名:高蒙  安俊琳  杭一纤  李用宇
作者单位:南京信息工程大学气象灾害省部共建教育部重点实验室,江苏 南京 210044
基金项目:国家自然科学基金项目(41305135和41275143)和中国科学院战略先导科技专项(B类)子课题(XDB05020206)共同资助.
摘    要:利用PMF模型和PCA/APCS模型对南京北郊大气VOCs进行定性和定量的源解析,并对比了两种模型的结果。结果表明:PMF模型对不同VOCs种类的模拟效果差别较大,而PCA/APCS对不同VOCs种类的模拟效果相近;PMF模型解析的源个数多于PCA/APCS模型,两种模型结果的源性质方面存在很大相似性,但PCA/APCS模型未能区分汽油挥发和汽车尾气源;两种模型源解析出的植物排放源、工业生产源的贡献率较接近,而其他源的贡献率存在差异,PCA/APCS模型解析的溶剂使用源的贡献率高于PMF模型结果,PMF模型解析出的汽油挥发+汽车尾气源的贡献率高于PCA/APCS模型结果。

关 键 词:VOCs    源解析  PMF模型    PCA/APCS模型  

Comparison of PMF and PCA/APCS for VOCs source apportionment in north suburb of Nanjing
GAO Meng,AN Jun-lin,HANG Yi-xian,LI Yong-yu.Comparison of PMF and PCA/APCS for VOCs source apportionment in north suburb of Nanjing[J].Journal of Meteorology and Environment,2014,30(1):43-50.
Authors:GAO Meng  AN Jun-lin  HANG Yi-xian  LI Yong-yu
Institution:Key Laboratory of Meteorological Disaster of Ministry of Education,?Nanjing University of Information Science & Technology,?Nanjing 210044, China
Abstract:The PMF model and PCA/APCS model were used to apportion atmospheric VOCs qualitatively and quantitatively in Nanjing, and both results were compared. The results show that the simulation result for the differ- ent types' VOCs by the PMF model significantly differs ,while it is similar to each other by the PCA/APCS mod- el. The number of sources apportioned by the PMF model is greater than that by the PCA/APCS model. Both source profiles are similar, while the PCA/APCS model fails to distinguish gasoline evaporation and vehicle ex- haust emission. The contributions of plant emission and industrial production apportioned by the two models are close, while those of the other sources differ. The contribution of solvent use is greater for the PCA/APCS model than for the PMF model, while the contribution of gasoline evaporation plus vehicle exhaust is greater for the PMF model than for the PCA/APCS.
Keywords:VOCs  Source apportionment  PMF model  PCA/APCS model
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